ICCAS OpenIR
Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal
Luo, Zhenhua1; Wei, Liuhe2; Li, Wanwan1; Liu, Feng1; Zhao, Tong1
2008-07-05
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume109Issue:1Pages:525-529
AbstractAn isothermal differential scanning calorimetry (DSC) study on the cure kinetics was performed on N-(3-acetylenephenyl)maleimide (3-APMI) monomer to determine a suitable cure model. The 3-APMI monomer reported in our prior article was a novel aromatic maleimide monomer with an acetylene terminal that would be an ideal candidate for heat-resistant composites. The isothermal DSC study was carried out in the temperature range 150-200 degrees C. Although the cure temperatures were different, the shapes of the conversion curves were similar, and all of the cure reactions could be described by an nth-order kinetic model. In particular, the cure reaction at the initial stage was a first-order kinetic reaction. The cure kinetic parameters of the 3-APMI monomer, including the reaction model, activation energy, and frequency factor, were determined. This information was very useful for defining the process parameters, final properties, and quality control of the cured 3-APMI monomer. (c) 2008 Wiley Periodicals, Inc.
KeywordThermosets Curing Of Polymers Differential Scanning Calorimetry (Dsc) Kinetics
DOI10.1002/app.28090
Indexed BySCI
Language英语
WOS IDWOS:000255626700067
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65462
Collection中国科学院化学研究所
Corresponding AuthorZhao, Tong
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450002, Peoples R China
Recommended Citation
GB/T 7714
Luo, Zhenhua,Wei, Liuhe,Li, Wanwan,et al. Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2008,109(1):525-529.
APA Luo, Zhenhua,Wei, Liuhe,Li, Wanwan,Liu, Feng,&Zhao, Tong.(2008).Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal.JOURNAL OF APPLIED POLYMER SCIENCE,109(1),525-529.
MLA Luo, Zhenhua,et al."Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal".JOURNAL OF APPLIED POLYMER SCIENCE 109.1(2008):525-529.
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