A mercury(II)-radical complex with a 1D ladder structure

doi:10.1080/00958970701598951

ICCAS OpenIR

	A mercury(II)-radical complex with a 1D ladder structure
	Zhang, Jian-Ying 1,2; Liu, Cai-Ming 1; Zhang, De-Qing 1; Zhu, Dao-Ben 1
	2008
Source Publication	JOURNAL OF COORDINATION CHEMISTRY
ISSN	0095-8972
Volume	61 Issue:8 Pages:1325-1332
Abstract	Interaction of HgI2 with a new long rigid nitronyl nitroxide radical ligand, 2-[4-(2-pyridin-4-yl-vinyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (L), leads to the formation of the mercury-radical complex [Hg2I4L2](n) (1). The single crystal structure analysis reveals that 1 exhibits a one-dimensional (1D) ladder structure. Magnetic susceptibility data of 1 were simulated by a uniform chain model composed of the NIT-NIT dimers, indicating that there exist an antiferromagnetic exchange between the nitroxides within the dimer (J(1) = -8.41 cm(-1)) and a very weak interdimer antiferromagnetic interaction (J(c) = -0.39 cm(-1)).
Keyword	Nitronyl Nitroxide Complex Mercury Complex Ladder Structure Magnetic Properties
DOI	10.1080/00958970701598951
Indexed By	SCI
Language	英语
WOS ID	WOS:000255275800016
Publisher	TAYLOR & FRANCIS LTD
Citation statistics	Cited Times:1[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.iccas.ac.cn/handle/121111/65426
Collection	中国科学院化学研究所
Corresponding Author	Liu, Cai-Ming
Affiliation	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. A mercury(II)-radical complex with a 1D ladder structure[J]. JOURNAL OF COORDINATION CHEMISTRY,2008,61(8):1325-1332.
APA	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,&Zhu, Dao-Ben.(2008).A mercury(II)-radical complex with a 1D ladder structure.JOURNAL OF COORDINATION CHEMISTRY,61(8),1325-1332.
MLA	Zhang, Jian-Ying,et al."A mercury(II)-radical complex with a 1D ladder structure".JOURNAL OF COORDINATION CHEMISTRY 61.8(2008):1325-1332.

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