ICCAS OpenIR
A mercury(II)-radical complex with a 1D ladder structure
Zhang, Jian-Ying1,2; Liu, Cai-Ming1; Zhang, De-Qing1; Zhu, Dao-Ben1
2008
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume61Issue:8Pages:1325-1332
AbstractInteraction of HgI2 with a new long rigid nitronyl nitroxide radical ligand, 2-[4-(2-pyridin-4-yl-vinyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (L), leads to the formation of the mercury-radical complex [Hg2I4L2](n) (1). The single crystal structure analysis reveals that 1 exhibits a one-dimensional (1D) ladder structure. Magnetic susceptibility data of 1 were simulated by a uniform chain model composed of the NIT-NIT dimers, indicating that there exist an antiferromagnetic exchange between the nitroxides within the dimer (J(1) = -8.41 cm(-1)) and a very weak interdimer antiferromagnetic interaction (J(c) = -0.39 cm(-1)).
KeywordNitronyl Nitroxide Complex Mercury Complex Ladder Structure Magnetic Properties
DOI10.1080/00958970701598951
Indexed BySCI
Language英语
WOS IDWOS:000255275800016
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65426
Collection中国科学院化学研究所
Corresponding AuthorLiu, Cai-Ming
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. A mercury(II)-radical complex with a 1D ladder structure[J]. JOURNAL OF COORDINATION CHEMISTRY,2008,61(8):1325-1332.
APA Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,&Zhu, Dao-Ben.(2008).A mercury(II)-radical complex with a 1D ladder structure.JOURNAL OF COORDINATION CHEMISTRY,61(8),1325-1332.
MLA Zhang, Jian-Ying,et al."A mercury(II)-radical complex with a 1D ladder structure".JOURNAL OF COORDINATION CHEMISTRY 61.8(2008):1325-1332.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Jian-Ying]'s Articles
[Liu, Cai-Ming]'s Articles
[Zhang, De-Qing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Jian-Ying]'s Articles
[Liu, Cai-Ming]'s Articles
[Zhang, De-Qing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Jian-Ying]'s Articles
[Liu, Cai-Ming]'s Articles
[Zhang, De-Qing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.