ICCAS OpenIR
Improving enantioselectivity via rationally tuning electronic effects of catalysts in the organocatalytic asymmetric aldol reaction
Du, Juanjuan3; Li, Zhiyi3; Du, Da-Ming3; Xu, Jiaxi1,2,3
2008
Source PublicationARKIVOC
ISSN1424-6376
Pages145-156
AbstractBoth steric repulsion and electronic effect govern the stereoselectivity in asymmetric catalysis. Rationally electronic-tuned N-(2-hydroxylphenyl)-(S)-prolinamide derived catalysts were designed, synthesized, and evaluated in the asymmetric aldol reaction. The results indicate that the enantiomeric ratios of products correlate well with the Hammett constants, which confirms that the enantioselectivity was improved via rationally tuning catalyst electronic effects.
KeywordAsymmetric Aldol Reaction Electronic Effect Electronic Tuning Enantioselectivity Organocatalyst
Indexed BySCI
Language英语
WOS IDWOS:000265191300013
PublisherARKAT USA INC
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65396
Collection中国科学院化学研究所
Corresponding AuthorXu, Jiaxi
Affiliation1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
2.Beijing Univ Chem Technol, Fac Sci, Beijing 100029, Peoples R China
3.Peking Univ, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Du, Juanjuan,Li, Zhiyi,Du, Da-Ming,et al. Improving enantioselectivity via rationally tuning electronic effects of catalysts in the organocatalytic asymmetric aldol reaction[J]. ARKIVOC,2008:145-156.
APA Du, Juanjuan,Li, Zhiyi,Du, Da-Ming,&Xu, Jiaxi.(2008).Improving enantioselectivity via rationally tuning electronic effects of catalysts in the organocatalytic asymmetric aldol reaction.ARKIVOC,145-156.
MLA Du, Juanjuan,et al."Improving enantioselectivity via rationally tuning electronic effects of catalysts in the organocatalytic asymmetric aldol reaction".ARKIVOC (2008):145-156.
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