ICCAS OpenIR
Synthesis and properties of two second-order nonlinear optical polymers: an attempt toward the balance between nonlinearity and transparence against intrinsic trade-off
Su-Yue, Li1; Zhong-An, Li1; Zhi-Chao, Zhu1; Wei, Zhang1; Ting, Huang1; Zhen, Li1; Cheng, Ye2; Jin-Gui, Qin1
2008-02-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume26Issue:2Pages:328-332
AbstractTwo new poly(arylene ether sulfone)s (P1 and P2) with two new accepting group (TCF)-based chromophores (1 and 2) in side chains, respectively, were designed and synthesized. The two chromophores contain the same electron donating group (dialkylamino group) and the same accepting group (TCF), but different conjugation bridges. Compound 2 contains a combined conjugation bridge (phenyl-diazene plus styrene), but the bridge of 1 is much shorter (styrene only). A variety of optical properties were studied. Compared with P1, P2 exhibited comparable nonlinear optical coefficient (d(33)) and better transparency (the maximum absorption was blue-shifted by 16 nm), though the conjugation bridge of chromophore 2 in P2 was much longer than that of 1 in P1. This result may help design nonlinear optical polymers achieving the balance between nonlinearity and transparence against the intrinsic trade-off.
KeywordNonlinear Optics Combined Conjugation Bridge Nonlinearity-transparency Trade-off
Indexed BySCI ; IC
Language英语
WOS IDWOS:000253710900017
PublisherWILEY-BLACKWELL
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65368
Collection中国科学院化学研究所
Corresponding AuthorSu-Yue, Li
Affiliation1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Su-Yue, Li,Zhong-An, Li,Zhi-Chao, Zhu,et al. Synthesis and properties of two second-order nonlinear optical polymers: an attempt toward the balance between nonlinearity and transparence against intrinsic trade-off[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(2):328-332.
APA Su-Yue, Li.,Zhong-An, Li.,Zhi-Chao, Zhu.,Wei, Zhang.,Ting, Huang.,...&Jin-Gui, Qin.(2008).Synthesis and properties of two second-order nonlinear optical polymers: an attempt toward the balance between nonlinearity and transparence against intrinsic trade-off.CHINESE JOURNAL OF CHEMISTRY,26(2),328-332.
MLA Su-Yue, Li,et al."Synthesis and properties of two second-order nonlinear optical polymers: an attempt toward the balance between nonlinearity and transparence against intrinsic trade-off".CHINESE JOURNAL OF CHEMISTRY 26.2(2008):328-332.
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