ICCAS OpenIR
Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts
Zhao, Chen2; Gan, Weijia2; Fan, Xiaobing2; Cai, Zhipeng2; Dyson, Paul J.; Kou, Yuan2
2008-03-10
Source PublicationJOURNAL OF CATALYSIS
ISSN0021-9517
Volume254Issue:2Pages:244-250
AbstractA biphasic approach to the dehydroaromatization of bioderived limonene into water-insoluble p-cymene using soluble Pd nanoparticle catalysts in an aqueous phase (>= 150 degrees C, 2 bar H-2) was successfully achieved with a conversion of 93% and a selectivity of 82%. The Pd nanoparticles, operating under forcing conditions (180 degrees C, 2 bar H-2), can be recycled at least four times without noticeable degradation. The effects of temperature, pressure, reaction time, pH, catalyst concentration, metal type, the type and amount of polymer stabilizer, and the preparation method were systematically investigated to optimize the process and provide insight into the mechanisms involved. (C) 2008 Elsevier Inc. All rights reserved.
KeywordLimonene P-cymene Dehydroaromatization Palladium Nanoparticles Biphasic Catalysis Terpene Poly(N-vinyl-2-pyrrolidone) Biomass
DOI10.1016/j.jcat.2008.01.003
Indexed BySCI
Language英语
WOS IDWOS:000255533700010
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65310
Collection中国科学院化学研究所
Corresponding AuthorDyson, Paul J.
Affiliation1.Ecole Polytech Fed Lausanne, Inst Sci Ingn Chim, CH-1015 Lausanne, Switzerland
2.Peking Univ, Coll Chem & Mol Engn, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Chen,Gan, Weijia,Fan, Xiaobing,et al. Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts[J]. JOURNAL OF CATALYSIS,2008,254(2):244-250.
APA Zhao, Chen,Gan, Weijia,Fan, Xiaobing,Cai, Zhipeng,Dyson, Paul J.,&Kou, Yuan.(2008).Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts.JOURNAL OF CATALYSIS,254(2),244-250.
MLA Zhao, Chen,et al."Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts".JOURNAL OF CATALYSIS 254.2(2008):244-250.
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