ICCAS OpenIR
Liquid-phase synthesis of methyl formate via heterogeneous carbonylation of methanol over a soluble copper nanocluster catalyst
He, Ling; Liu, Haichao; Xiao, Chao-xian; Kou, Yuan
2008
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume10Issue:6Pages:619-622
AbstractLiquid-phase synthesis of methyl formate (MF) was achieved by green carbonylation of methanol with CO on a soluble copper nanocluster catalyst with high activities (e. g. 2.7-6.1 mol(MF) mol(Cu)(-1) h(-1)) and 100% MF selectivities under mild reaction conditions (353-443 K, 0.3-3.0 MPa CO), showing that the Cu nanoclusters can potentially replace the caustic catalysts of alkaline metal alkoxides (e. g. CH(3)ONa), required for the current carbonylation process in industry.
DOI10.1039/b804459g
Indexed BySCI
Language英语
WOS IDWOS:000256388600005
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65284
Collection中国科学院化学研究所
Corresponding AuthorHe, Ling
AffiliationPeking Univ, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
He, Ling,Liu, Haichao,Xiao, Chao-xian,et al. Liquid-phase synthesis of methyl formate via heterogeneous carbonylation of methanol over a soluble copper nanocluster catalyst[J]. GREEN CHEMISTRY,2008,10(6):619-622.
APA He, Ling,Liu, Haichao,Xiao, Chao-xian,&Kou, Yuan.(2008).Liquid-phase synthesis of methyl formate via heterogeneous carbonylation of methanol over a soluble copper nanocluster catalyst.GREEN CHEMISTRY,10(6),619-622.
MLA He, Ling,et al."Liquid-phase synthesis of methyl formate via heterogeneous carbonylation of methanol over a soluble copper nanocluster catalyst".GREEN CHEMISTRY 10.6(2008):619-622.
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