ICCAS OpenIR
HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds
Gerones, Mariana1; Erben, Mauricio F.1; Romano, Rosana M.1; Della Vedova, Carlos O.1; Yao, Li3; Ge, Maofa2,3
2008-03-20
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
ISSN1089-5639
Volume112Issue:11Pages:2228-2234
AbstractSmall penta-atomic molecules like FC(O)SCl and ClC(O)SCl have been analyzed by using both photoelectron spectroscopy (PES) and results derived from the use of synchrotron radiation in the same energy range. For this second experiment total ion yield (TIY), photoelectron photoion coincidence (PEPICO), and partial ion yield (PIY) spectra have been recorded. This set of data together with results obtained by computational chemistry allow us to study electronic properties and the ionization channels of both species. Thus, whereas the photodissociation behavior of FC(O)SCl can be divided into three well-defined energy regions, the fragmentation dynamics of ClC(O)SCl seems to be more complex. Nevertheless, simultaneous evaluation of the PES and valence synchrotron photoionization studies helps to clarify the molecular ionization processes.
DOI10.1021/jp7101034
Indexed BySCI
Language英语
WOS IDWOS:000253946100011
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65198
Collection中国科学院化学研究所
Corresponding AuthorGe, Maofa
Affiliation1.Natl Univ La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR CONICET, RA-1900 La Plata, Argentina
2.UNLP CIC CONICET, LaSeISiC, Lab Serv Ind & Sistema Cientifico, RA-1903 Gonnet, Argentina
3.Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Gerones, Mariana,Erben, Mauricio F.,Romano, Rosana M.,et al. HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2008,112(11):2228-2234.
APA Gerones, Mariana,Erben, Mauricio F.,Romano, Rosana M.,Della Vedova, Carlos O.,Yao, Li,&Ge, Maofa.(2008).HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds.JOURNAL OF PHYSICAL CHEMISTRY A,112(11),2228-2234.
MLA Gerones, Mariana,et al."HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds".JOURNAL OF PHYSICAL CHEMISTRY A 112.11(2008):2228-2234.
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