ICCAS OpenIR
O(2) activation and hydrolysis of Salan rare-earth metal alkyl complexes
Liu, Xinli; Cui, Dongmei
2008
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Issue28Pages:3747-3752
AbstractSalan ligated yttrium alkyl complex 1, L(1)Y(CH(2)SiMe(3))(THF) (Salan = L(1): [2-O-3,5-tBu(2)-C(6)H(2)CH(2)N(CH(3)) CH(2)](2)), was exposed to an oxygen/ nitrogen atmosphere to give a bimetallic alkoxide complex 4, [L(1)Y(mu-OCH(2)SiMe(3))](2). Whilst the lutetium counterparts 2 (L(1)Lu(CH(2)SiMe(3))(THF)) and 3 (L(2)Lu(CH(2)SiMe(3))(THF); L(2): [2-O-3-tBu-C(6)H(2)CH(2)N(CH(3)) CH(2)](2)) were hydrolysed with moist nitrogen to afford mixed hydroxy/silyloxy complexes 5 and 6 ([L(1,2)Lu(mu-OSiMe(3))(mu-OH) LuL(1,2)]), respectively.
DOI10.1039/b802282h
Indexed BySCI
Language英语
WOS IDWOS:000257509500016
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65024
Collection中国科学院化学研究所
Corresponding AuthorCui, Dongmei
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xinli,Cui, Dongmei. O(2) activation and hydrolysis of Salan rare-earth metal alkyl complexes[J]. DALTON TRANSACTIONS,2008(28):3747-3752.
APA Liu, Xinli,&Cui, Dongmei.(2008).O(2) activation and hydrolysis of Salan rare-earth metal alkyl complexes.DALTON TRANSACTIONS(28),3747-3752.
MLA Liu, Xinli,et al."O(2) activation and hydrolysis of Salan rare-earth metal alkyl complexes".DALTON TRANSACTIONS .28(2008):3747-3752.
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