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Investigations of the optical spectra and local structure for nickel(II) ions in XF2 (X = Mg, Zn) single crystals
Feng, W. -L.; Quan, X. -J.; Hu, N.
2008
Source PublicationPHILOSOPHICAL MAGAZINE LETTERS
ISSN0950-0839
Volume88Issue:4Pages:287-291
AbstractA complete diagonalization energy matrix method (CDM) is proposed for 3d(8) ions in orthorhombic site (D-2h) symmetry. As an application, the optical spectra of XF2 : Ni2+ (X = Mg, Zn) is well explained on the basis of both the CDM and the semi-self-consistent field d-orbital (semi-SCF d-orbital) theory. In addition, by establishing the relationship between the optical spectra and local structure, it has been possible to calculate the crystal structure parameters for XF2:Ni2+ from optical measurements on Ni2+ ions. The theoretical results are in good agreement with experimental findings.
DOI10.1080/09500830801935293
Indexed BySCI
Language英语
WOS IDWOS:000254066900006
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64996
Collection中国科学院化学研究所
Corresponding AuthorFeng, W. -L.
AffiliationChongqing Inst Technol, Dept Appl Phys, Chongqing 400050, Peoples R China
Recommended Citation
GB/T 7714
Feng, W. -L.,Quan, X. -J.,Hu, N.. Investigations of the optical spectra and local structure for nickel(II) ions in XF2 (X = Mg, Zn) single crystals[J]. PHILOSOPHICAL MAGAZINE LETTERS,2008,88(4):287-291.
APA Feng, W. -L.,Quan, X. -J.,&Hu, N..(2008).Investigations of the optical spectra and local structure for nickel(II) ions in XF2 (X = Mg, Zn) single crystals.PHILOSOPHICAL MAGAZINE LETTERS,88(4),287-291.
MLA Feng, W. -L.,et al."Investigations of the optical spectra and local structure for nickel(II) ions in XF2 (X = Mg, Zn) single crystals".PHILOSOPHICAL MAGAZINE LETTERS 88.4(2008):287-291.
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