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A neutral molecular-based layered magnet [Fe(C(2)O(4))(CH(3)OH)](n) exhibiting magnetic ordering at T(N)approximate to 23 K
Zhang, Bin1,2; Zhang, Yan3; Zhang, Jinbiao1,2; Lia, Junchao1,2; Zhu, Daoben1,2
2008
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Issue37Pages:5037-5040
AbstractSolvothermal synthesis of FeCl(2)center dot 4H(2)O and H(2)C(2)O(4)center dot 2H(2)O in methanol at 120 degrees C yielded yellow plate-like crystals of [Fe(C(2)O(4))(CH(3)OH)](n). Each iron atom is in a distorted octahedral environment, being bonded to four oxygen atoms from two bisbidentate oxalate anions, one O atom of a chelating oxalate anion and one O atom from a methanol molecule as an oxalate group bridging ligand in a five-coordination mode. The neutral layer of [Fe(C(2)O(4))(CH(3)OH)](n) with a [4,4] net along the ac plane. There is no interaction between layers. A long range magnetic ordering with spin canting at T(N) approximate to 23 K was observed and confirmed by AC susceptibility measurements.
DOI10.1039/b805776a
Indexed BySCI
Language英语
WOS IDWOS:000259380800012
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64990
Collection中国科学院化学研究所
Corresponding AuthorZhang, Bin
Affiliation1.Chinese Acad Sci, Organ Solid Lab, Beijing Natl Lab Mol Sci, CMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
3.Peking Univ, Dept Phys, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Bin,Zhang, Yan,Zhang, Jinbiao,et al. A neutral molecular-based layered magnet [Fe(C(2)O(4))(CH(3)OH)](n) exhibiting magnetic ordering at T(N)approximate to 23 K[J]. DALTON TRANSACTIONS,2008(37):5037-5040.
APA Zhang, Bin,Zhang, Yan,Zhang, Jinbiao,Lia, Junchao,&Zhu, Daoben.(2008).A neutral molecular-based layered magnet [Fe(C(2)O(4))(CH(3)OH)](n) exhibiting magnetic ordering at T(N)approximate to 23 K.DALTON TRANSACTIONS(37),5037-5040.
MLA Zhang, Bin,et al."A neutral molecular-based layered magnet [Fe(C(2)O(4))(CH(3)OH)](n) exhibiting magnetic ordering at T(N)approximate to 23 K".DALTON TRANSACTIONS .37(2008):5037-5040.
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