ICCAS OpenIR
Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model
Zheng, De-Sheng; Wang, Yuan; Liu, An-An; Wang, Hong-Fei
2008
Source PublicationINTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY
ISSN0144-235X
Volume27Issue:4Pages:629-664
AbstractThe aim of this work is to present a coherent description of the microscopic theory of surface nonlinear optical spectroscopy for solving practical problems in understanding the details of the molecular interface. We review the related issues and show that by following microscopic molecular optics theory, second harmonic generation (SHG), as well as sum-frequency generation vibrational spectroscopy (SFG-VS), radiation from a monolayer or submonolayer can be rigorously treated as the radiation from an induced dipole lattice at the interface. In this approach, the introduction of an infinitesimally thin polarization sheet as in macroscopic theory with the Maxwell equations and the boundary conditions is no longer necessary. As a direct consequence, the ambiguity of the unaccounted dielectric constant of the interfacial layer is no longer an issue. Moreover, the anisotropic two-dimensional microscopic local field factors can be explicitly defined with the linear polarizability tensors of the interfacial molecules. Based on the planewise dipole sum rule in the molecular monolayer, experimental tests of this microscopic treatment with SHG and SFG-VS are discussed.
KeywordInterface Submonolayer Molecular Orientation Second Harmonic Generation (Shg) Sum Frequency Generation Vibrational Spectroiscopy (Sfg-vs) Maxwell Equations
DOI10.1080/01442350802343981
Indexed BySCI
Language英语
WOS IDWOS:000260163300002
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:47[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64984
Collection中国科学院化学研究所
Corresponding AuthorWang, Hong-Fei
AffiliationChinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zheng, De-Sheng,Wang, Yuan,Liu, An-An,et al. Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,2008,27(4):629-664.
APA Zheng, De-Sheng,Wang, Yuan,Liu, An-An,&Wang, Hong-Fei.(2008).Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model.INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,27(4),629-664.
MLA Zheng, De-Sheng,et al."Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model".INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY 27.4(2008):629-664.
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