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Amphiphilic polymer brushes with alternating PCL and PEO grafts through radical copolymerization of styrenic and maleimidic macromonomers
Zhu, Hui2; Deng, Guohua1; Chen, Yongming2
2008-01-21
Source PublicationPOLYMER
ISSN0032-3861
Volume49Issue:2Pages:405-411
AbstractSynthesis of a novel amphiphilic polymer brush with a sequence of alternating poly(F-caprolactone) (PCL) and poly(ethylene oxide) (PEO) side chains through grafting-through approach is reported. This strategy consists of two steps: first, a PCL macromonomer carrying maleimide functional group (MI-PCL) and a PEO macromonomer with vinylbenzyl group (St-PEO) were prepared; then a conventional radical copolymerization of the MI-PCL and the St-PEO macromonomers was carried out to obtain the proto-type polymer brush. The reactivity ratios of two macromonomers were studied and the alternating sequence structure was proved. (c) 2007 Elsevier Ltd. All rights reserved.
KeywordCopolymerization Block Copolymers Grafted Polymers
DOI10.1016/j.polymer.2007.11.037
Indexed BySCI
Language英语
WOS IDWOS:000253266900006
PublisherELSEVIER SCI LTD
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64840
Collection中国科学院化学研究所
Corresponding AuthorDeng, Guohua
Affiliation1.S China Univ Technol, Coll Chem, Guangzhou 510640, Peoples R China
2.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Hui,Deng, Guohua,Chen, Yongming. Amphiphilic polymer brushes with alternating PCL and PEO grafts through radical copolymerization of styrenic and maleimidic macromonomers[J]. POLYMER,2008,49(2):405-411.
APA Zhu, Hui,Deng, Guohua,&Chen, Yongming.(2008).Amphiphilic polymer brushes with alternating PCL and PEO grafts through radical copolymerization of styrenic and maleimidic macromonomers.POLYMER,49(2),405-411.
MLA Zhu, Hui,et al."Amphiphilic polymer brushes with alternating PCL and PEO grafts through radical copolymerization of styrenic and maleimidic macromonomers".POLYMER 49.2(2008):405-411.
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