ICCAS OpenIR
Two-dimensional layer polyoxometalate-based inorganic metal-organic hybrid supramolecular networks woven by Cu center dot center dot center dot O-polyoxoanion short contact weak interactions
Liu, Cai-Ming; Zhang, Jian-Ying; Zhang, De-Qing
2008
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume61Issue:4Pages:627-639
AbstractTwo polyoxometalate-based inorganic metal-organic hybrid supramolecular complexes [Cu(2,2'-bpy)(2)](2)[(V2Mo5Mo7O38)-Mo-IV-Mo-V-O-VI(PO4)] (1) (2,2'-bpy = 2,2'-bipyridine) and [Cu(2,2'-bpy)(2)](2)[(MoMo11O36)-Mo-V-O-VI(PO4)] 3H(2)O (2), have been hydrothermally prepared and structurally characterized by single-crystal X-ray diffraction. Both complexes are constructed from polyoxoanions (the bivanadyl capped -Keggin polymolybdate anion [(V2Mo5Mo7O38)-Mo-IV-Mo-V-O-VI(PO4)](4-) for 1 and the reduced 12-molybdophosphate anion [(MoMo11O36)-Mo-V-O-VI(PO4)](4-) for 2) and copper(II) complex cations [Cu(2,2'-bpy)2]2+, forming two-dimensional (2D) layer network structures, in which the polyoxoanion and the complex fragment cation connect with each other through Cu center dot center dot center dot O-polyoxoanion short contact weak interactions, which mediate ferromagnetic interaction.
KeywordPolyoxometalate Hybrid Material Crystal Structure Weak Interaction Copper(Ii) Complex Magnetic Property
DOI10.1080/00958970701369791
Indexed BySCI
Language英语
WOS IDWOS:000253265700014
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64800
Collection中国科学院化学研究所
Corresponding AuthorLiu, Cai-Ming
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, Cai-Ming,Zhang, Jian-Ying,Zhang, De-Qing. Two-dimensional layer polyoxometalate-based inorganic metal-organic hybrid supramolecular networks woven by Cu center dot center dot center dot O-polyoxoanion short contact weak interactions[J]. JOURNAL OF COORDINATION CHEMISTRY,2008,61(4):627-639.
APA Liu, Cai-Ming,Zhang, Jian-Ying,&Zhang, De-Qing.(2008).Two-dimensional layer polyoxometalate-based inorganic metal-organic hybrid supramolecular networks woven by Cu center dot center dot center dot O-polyoxoanion short contact weak interactions.JOURNAL OF COORDINATION CHEMISTRY,61(4),627-639.
MLA Liu, Cai-Ming,et al."Two-dimensional layer polyoxometalate-based inorganic metal-organic hybrid supramolecular networks woven by Cu center dot center dot center dot O-polyoxoanion short contact weak interactions".JOURNAL OF COORDINATION CHEMISTRY 61.4(2008):627-639.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Cai-Ming]'s Articles
[Zhang, Jian-Ying]'s Articles
[Zhang, De-Qing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Cai-Ming]'s Articles
[Zhang, Jian-Ying]'s Articles
[Zhang, De-Qing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Cai-Ming]'s Articles
[Zhang, Jian-Ying]'s Articles
[Zhang, De-Qing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.