ICCAS OpenIR
Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures
Qi, Jian1; Huang, Kun1; Gao, Xiuxiang1; Li, Huizhen1,4; Liu, Shaoxuan1; Zhao, Ying2; Xu, Yizhuang1; Wu, Jinguang1; Noda, Isao3
2008-07-30
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
ISSN0022-2860
Volume883Pages:116-123
AbstractWeak interactions between lanthanide (III) ions and organic ligands in solution mixtures are studied by using two-dimensional synchronous spectroscopy together with "Orthogonal Sample Design" (OSD) scheme that can effectively remove the interfering cross peaks in 2D synchronous spectrum. Two representative chemical systems are investigated and discussed here: (1) PrCl(3)/butanone in ethanol solution, where weak coordinative interaction between Pr(3+) and carbonyl group from butanone is characterized by using 2D UV/IR heterogeneous spectroscopy; and (2) NdCl(3)/5-sulfosalicylic acid in aqueous solution, where the interaction between Nd(3+)/5-sulfosalicylic acid is investigated by using 2D UV spectra. The cross peaks occurred in the 2D spectra confirm the weak interactions between lanthanide (111) ions and corresponding molecules where no observable variation occurs in conventional I D spectra. (C) 2008 Elsevier B.V. All rights reserved.
KeywordOrthogonal Sample Design Scheme 2d Correlation Analysis Synchronous Spectrum Cross Peaks Intermolecular Interaction
DOI10.1016/j.molstruc.2008.01.036
Indexed BySCI ; ISTP
Language英语
WOS IDWOS:000257603000017
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64780
Collection中国科学院化学研究所
Corresponding AuthorXu, Yizhuang
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Procter & Gamble Co, W Chester, OH 45069 USA
4.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Recommended Citation
GB/T 7714
Qi, Jian,Huang, Kun,Gao, Xiuxiang,et al. Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures[J]. JOURNAL OF MOLECULAR STRUCTURE,2008,883:116-123.
APA Qi, Jian.,Huang, Kun.,Gao, Xiuxiang.,Li, Huizhen.,Liu, Shaoxuan.,...&Noda, Isao.(2008).Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures.JOURNAL OF MOLECULAR STRUCTURE,883,116-123.
MLA Qi, Jian,et al."Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures".JOURNAL OF MOLECULAR STRUCTURE 883(2008):116-123.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Qi, Jian]'s Articles
[Huang, Kun]'s Articles
[Gao, Xiuxiang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Qi, Jian]'s Articles
[Huang, Kun]'s Articles
[Gao, Xiuxiang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Qi, Jian]'s Articles
[Huang, Kun]'s Articles
[Gao, Xiuxiang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.