Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures

doi:10.1016/j.molstruc.2008.01.036

ICCAS OpenIR

	Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures
	Qi, Jian 1; Huang, Kun 1; Gao, Xiuxiang 1; Li, Huizhen 1,4; Liu, Shaoxuan 1; Zhao, Ying 2; Xu, Yizhuang 1; Wu, Jinguang 1; Noda, Isao 3
	2008-07-30
Source Publication	JOURNAL OF MOLECULAR STRUCTURE
ISSN	0022-2860
Volume	883 Pages:116-123
Abstract	Weak interactions between lanthanide (III) ions and organic ligands in solution mixtures are studied by using two-dimensional synchronous spectroscopy together with "Orthogonal Sample Design" (OSD) scheme that can effectively remove the interfering cross peaks in 2D synchronous spectrum. Two representative chemical systems are investigated and discussed here: (1) PrCl(3)/butanone in ethanol solution, where weak coordinative interaction between Pr(3+) and carbonyl group from butanone is characterized by using 2D UV/IR heterogeneous spectroscopy; and (2) NdCl(3)/5-sulfosalicylic acid in aqueous solution, where the interaction between Nd(3+)/5-sulfosalicylic acid is investigated by using 2D UV spectra. The cross peaks occurred in the 2D spectra confirm the weak interactions between lanthanide (111) ions and corresponding molecules where no observable variation occurs in conventional I D spectra. (C) 2008 Elsevier B.V. All rights reserved.
Keyword	Orthogonal Sample Design Scheme 2d Correlation Analysis Synchronous Spectrum Cross Peaks Intermolecular Interaction
DOI	10.1016/j.molstruc.2008.01.036
Indexed By	SCI ; ISTP
Language	英语
WOS ID	WOS:000257603000017
Publisher	ELSEVIER SCIENCE BV
Citation statistics	Cited Times:25[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.iccas.ac.cn/handle/121111/64780
Collection	中国科学院化学研究所
Corresponding Author	Xu, Yizhuang
Affiliation	1.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Procter & Gamble Co, W Chester, OH 45069 USA 4.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Recommended Citation GB/T 7714	Qi, Jian,Huang, Kun,Gao, Xiuxiang,et al. Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures[J]. JOURNAL OF MOLECULAR STRUCTURE,2008,883:116-123.
APA	Qi, Jian.,Huang, Kun.,Gao, Xiuxiang.,Li, Huizhen.,Liu, Shaoxuan.,...&Noda, Isao.(2008).Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures.JOURNAL OF MOLECULAR STRUCTURE,883,116-123.
MLA	Qi, Jian,et al."Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures".JOURNAL OF MOLECULAR STRUCTURE 883(2008):116-123.

Files in This Item:
There are no files associated with this item.

If you have any objections to this item, please fill out the form below and the administrator will contact you as soon as possible.
Content:
Email：	*
Institution:
Verification Code:	Refresh

Any comments and suggestions are welcomed.
Title:	*
Content:
Email：	*
Verification Code:	Refresh

中国科学院化学研究所机构知识库