ICCAS OpenIR
Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker
Zou, Yingping1,2,5; Sang, Guangyi1,2,5; Wan, Meixiu1,2,3,4; Tan, Songting3,4; Li, Yongfang1,2
2008-07-21
Source PublicationMACROMOLECULAR CHEMISTRY AND PHYSICS
ISSN1022-1352
Volume209Issue:14Pages:1454-1462
AbstractThree polythiophenes with 5%, 10% and 15%triphenylaminetrivinylene (TPAV) as bridge linker, PT-TPAV5, PT-TPAV10 and PT-TPAV15, were synthesized. The Wittig-Horner-Emmons reaction and the Stille method were employed to synthesize these polymers. The polythiophenes were subsequently used in bulk-heterojunction polymer solar cells (PSCs) as donor materials. The polymers exhibited a striking and reversible color change after the oxidation of the polymer films. The power conversion efficiencies of the PSCs based on PT-TPAV5, PT-TPAV10 and PT-TPAV15 as donors and PCBM as acceptor were 0.17%, 0.50%, and 0.35%, respectively, under the illumination of AM 1.5, 100 mW.cm(-2).
KeywordConducting Polymers Electrochemistry Photochemistry Synthesis
DOI10.1002/macp.200800083
Indexed BySCI ; IC
Language英语
WOS IDWOS:000258282400006
PublisherWILEY-BLACKWELL
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Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64770
Collection中国科学院化学研究所
Corresponding AuthorLi, Yongfang
Affiliation1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
3.Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
4.Xiangtan Univ, Inst Polymer Mat, Xiangtan 411105, Peoples R China
5.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Zou, Yingping,Sang, Guangyi,Wan, Meixiu,et al. Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2008,209(14):1454-1462.
APA Zou, Yingping,Sang, Guangyi,Wan, Meixiu,Tan, Songting,&Li, Yongfang.(2008).Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker.MACROMOLECULAR CHEMISTRY AND PHYSICS,209(14),1454-1462.
MLA Zou, Yingping,et al."Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker".MACROMOLECULAR CHEMISTRY AND PHYSICS 209.14(2008):1454-1462.
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