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Syntheses and structures of mononuclear and binuclear transition metal complexes (Cu, Zn, Ni) with (salicylideneglycine and imidazole)
Xing, Yong Heng1; Han, Jing1; Zhou, Guang Hua1; Sun, Zheng2; Zhang, Xing Jing1; Zhang, Bao Li1; Zhang, Yuan Hong1; Yuan, Hou Qun1; Ge, Mao Fa2
2008
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume61Issue:5Pages:715-730
AbstractFour transition metal (Cu(II), Zn(II) and Ni(II)) complexes with a Schiff-base ligand (salicylideneglycine) have been synthesized. All complexes have been characterized by elemental analysis, IR spectra and UV-vis spectroscopy. Single-crystal analyses were performed with (C9H7NO3)Cu(C3H4N2) (1), (C9H7NO3)Zn(C3H4N2)(2) (2), (C9H7NO3)(2)Ni-2(C3H4N2)(4) (3) and (C9H7NO3)Ni(C3H4N2)(2)(C4H5N2O) CH3OH 0.5H(2)O (4) and fluorescence spectra and thermogravimetric analyses were also carried out. Structural analyses show that 1, 2 and 4 have similar coordinated modes with the tridentate amino-Schiff-base ligand, but differ from the binuclear nickel complex 3. The tridentate amino-Schiff-base ligand contains aliphatic nitrogen, phenoxy, and carboxylic oxygen as three donor atoms. In addition, inter- and intra-molecular hydrogen bonds are also discussed.
KeywordTransition Metal Complexes Salicylideneglycine Ligand Supramolecular Assembly Hydrogen Bond Crystal Structures
DOI10.1080/00958970701389989
Indexed BySCI
Language英语
WOS IDWOS:000253728900007
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64588
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Bioinorgan Lab, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xing, Yong Heng,Han, Jing,Zhou, Guang Hua,et al. Syntheses and structures of mononuclear and binuclear transition metal complexes (Cu, Zn, Ni) with (salicylideneglycine and imidazole)[J]. JOURNAL OF COORDINATION CHEMISTRY,2008,61(5):715-730.
APA Xing, Yong Heng.,Han, Jing.,Zhou, Guang Hua.,Sun, Zheng.,Zhang, Xing Jing.,...&Ge, Mao Fa.(2008).Syntheses and structures of mononuclear and binuclear transition metal complexes (Cu, Zn, Ni) with (salicylideneglycine and imidazole).JOURNAL OF COORDINATION CHEMISTRY,61(5),715-730.
MLA Xing, Yong Heng,et al."Syntheses and structures of mononuclear and binuclear transition metal complexes (Cu, Zn, Ni) with (salicylideneglycine and imidazole)".JOURNAL OF COORDINATION CHEMISTRY 61.5(2008):715-730.
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