ICCAS OpenIR
{2-[1-(2,6-Diisopropylphenylimino)ethyllpyridyl}palladium dibromide polymorphs originating from different Br center dot center dot center dot pi and C-H center dot center dot center dot Br contacts
Zhang, Wenjuan1; Tang, Xiubo1; Ma, Hongwei1; Sun, Wen-Hua1; Janiak, Christoph2
2008-06-01
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue18Pages:2830-2836
Abstract{2-[1-(2,6-Diisopropylphenylimino)ethyllpyridyl)palladium dibromide (1) was synthesized and crystallized as red crystals from chloroform in the monoclinic space group P2(1)/c or as yellow crystals from methanol in the triclinic space group P (1) over bar. Other solvents, such as THF and acetonitrile, gave mixtures of red and yellow crystals. With very little conformational differences between the molecules in the dimorphs of 1 the crystal packing is a herringbone array in I-red and a parallel array in 1-yellow, with the supramolecular interactions differing in the Br center dot center dot center dot pi and C-H center dot center dot center dot Br contacts. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
KeywordPalladium Complexes Polymorphism Supramolecular Interactions C-h Center Dot Center Dot Center Dot Br Br Center Dot Center Dot Center Dot Pi
DOI10.1002/ejic.200800260
Indexed BySCI
Language英语
WOS IDWOS:000257260000005
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:39[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64374
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany
Recommended Citation
GB/T 7714
Zhang, Wenjuan,Tang, Xiubo,Ma, Hongwei,et al. {2-[1-(2,6-Diisopropylphenylimino)ethyllpyridyl}palladium dibromide polymorphs originating from different Br center dot center dot center dot pi and C-H center dot center dot center dot Br contacts[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2008(18):2830-2836.
APA Zhang, Wenjuan,Tang, Xiubo,Ma, Hongwei,Sun, Wen-Hua,&Janiak, Christoph.(2008).{2-[1-(2,6-Diisopropylphenylimino)ethyllpyridyl}palladium dibromide polymorphs originating from different Br center dot center dot center dot pi and C-H center dot center dot center dot Br contacts.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(18),2830-2836.
MLA Zhang, Wenjuan,et al."{2-[1-(2,6-Diisopropylphenylimino)ethyllpyridyl}palladium dibromide polymorphs originating from different Br center dot center dot center dot pi and C-H center dot center dot center dot Br contacts".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .18(2008):2830-2836.
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