ICCAS OpenIR
Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups
Zou Ting1; Lu Liang1; Liu Xiu-Li1; Zhang Zhan1; Wang Li-Bing1; Fu Xian-Lei1; Gao Guo-Hua1; Kou Yuan2; He Ming-Yuan1
2008-08-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume26Issue:8Pages:1469-1480
AbstractA series of asymmetric methide anion based ionic liquids containing nitrile groups have been synthesized for the first time Using the method of ion-exchange between sodium/potassium methide and various quaternary bromide/chloride salts of trimethylamine, triethylamine, tributylamine, N-methylpyrrolidine, And N-methylimidazole.. All of the functionalised ionic liquids were characterized by IR, (1)H, (13)C NMR, MS and elemental analysis. The decomposition temperature of the ionic liquids measured via TGA ranged from 219 to 339 degrees C. The functionalised ionic liquid, [Bmim][C(CN)(2)COCH(3)], was used as a ligand for Suzuki coupling reaction. The yields Of the Coupling reaction increased 10%-15% by the addition of the functionalised ionic liquid, [Bmim][C(CN)(2)COCH(3)].
KeywordIonic Liquid Methide Anion Nitrile Group Asymmetric Coupling Reaction
Indexed BySCI ; IC
Language英语
WOS IDWOS:000258940100021
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64342
Collection中国科学院化学研究所
Corresponding AuthorGao Guo-Hua
Affiliation1.E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Dept Chem, Shanghai 200062, Peoples R China
2.Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Zou Ting,Lu Liang,Liu Xiu-Li,et al. Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(8):1469-1480.
APA Zou Ting.,Lu Liang.,Liu Xiu-Li.,Zhang Zhan.,Wang Li-Bing.,...&He Ming-Yuan.(2008).Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups.CHINESE JOURNAL OF CHEMISTRY,26(8),1469-1480.
MLA Zou Ting,et al."Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups".CHINESE JOURNAL OF CHEMISTRY 26.8(2008):1469-1480.
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