ICCAS OpenIR
Organic-inorganic hybrid aligned by the ligand-ligand hydrogen bonds by using pyridyl-substituted oxalamides as the building blocks
Zeng, Qingdao1; Li, Min2; Wu, Dongxia1; Lei, Shengbin1; Liu, Caiming2; Piao, Lingyu1; Yang, Yanlian1; An, Shiyan3; Wang, Chen1
2008-03-01
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume8Issue:3Pages:869-876
AbstractPyridyl-substituted oxalamides, L(1) (4-pyCH(2)NHCOCONHCH(2)Py-4), L(2) (3-pyCH(2)NHCOCONHCH(2)PY-3), and L(3) (2-pyCH(2)NHCOCONHCH(2)PY-2), with HgI(2) and/or CuBr(2), form three new supramolecular complexes, [Hg(3)L(1)I(6)](infinity) (1), {[Cu(2)(L(2))(4)Br(2)]center dot Br(2)center dot 4H(2)O}(infinity) (2), and [Hg(L(3))(2)I(2)](infinity) (3), respectively. The complexes 1-3 are aligned by the oxalamide-oxalamide N-H center dot center dot center dot O hydrogen bonds between layers, and their crystal structures have been determined by single-crystal X-ray diffraction. Complex 1 forms a two-dimensional (2D) zigzag sheet architecture extending along the c-direction bridged by L(1) ligand and HgI(2), Complex 2 forms an interesting planar 2D (4,4) network with the uncoordinated Br(-) anions and H(2)O molecules located in the cavities. Complex 3 forms [2 + 2] metallomacrocycles, which are linked with the mu(2)-bridged I atom and stacked to-ether by intermolecular oxalamide-oxalamide hydrogen bonds and by edge-to-face T-stacking between the pyridyl rings to form the desired supramolecular tubular structure along the a-axis. After the removal of the solvent molecules, solid 2 exhibits a permanent porosity verified by a N(2) sorption isotherm with a N(2) uptake of approximately 1258 cm(3)/g (STP) and a Langmuir surface area of 2102 m(2)/g.
DOI10.1021/cg070506u
Indexed BySCI
Language英语
WOS IDWOS:000253800200025
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64334
Collection中国科学院化学研究所
Corresponding AuthorZeng, Qingdao
Affiliation1.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
3.China Acad Telecommun Res MII, Environm Protect Test Dept, China Acad Telecommun Technol Labs, Beijing 100045, Peoples R China
Recommended Citation
GB/T 7714
Zeng, Qingdao,Li, Min,Wu, Dongxia,et al. Organic-inorganic hybrid aligned by the ligand-ligand hydrogen bonds by using pyridyl-substituted oxalamides as the building blocks[J]. CRYSTAL GROWTH & DESIGN,2008,8(3):869-876.
APA Zeng, Qingdao.,Li, Min.,Wu, Dongxia.,Lei, Shengbin.,Liu, Caiming.,...&Wang, Chen.(2008).Organic-inorganic hybrid aligned by the ligand-ligand hydrogen bonds by using pyridyl-substituted oxalamides as the building blocks.CRYSTAL GROWTH & DESIGN,8(3),869-876.
MLA Zeng, Qingdao,et al."Organic-inorganic hybrid aligned by the ligand-ligand hydrogen bonds by using pyridyl-substituted oxalamides as the building blocks".CRYSTAL GROWTH & DESIGN 8.3(2008):869-876.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zeng, Qingdao]'s Articles
[Li, Min]'s Articles
[Wu, Dongxia]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zeng, Qingdao]'s Articles
[Li, Min]'s Articles
[Wu, Dongxia]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zeng, Qingdao]'s Articles
[Li, Min]'s Articles
[Wu, Dongxia]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.