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Chiral bifunctional N-heterocyclic carbenes: Synthesis and application in the aza-Morita-Baylis-Hillman reaction
He, Lin; Zhang, Yan-Rong; Huang, Xue-Liang; Ye, Song
2008-09-02
Source PublicationSYNTHESIS-STUTTGART
ISSN0039-7881
Issue17Pages:2825-2829
AbstractA series of chiral bifunctional N-heterocyclic carbene (NHC) precursors with a proximal hydroxy group were smoothly prepared from L-pyroglutamic acid. Promising enantiomeric excesses (up to 44% ee) were achieved for the bifunctional NHC-catalyzed enantioselective aza-Morita-Baylis-Hillman reaction of cyclopent-2-enone with N-tosylphenylmethanimine.
KeywordN-heterocyclic Carbenes Bifunctional Catalysts Enantioselective Synthesis Aza-morita-baylis-hillman Reaction
DOI10.1055/s-2008-1067216
Indexed BySCI ; IC
Language英语
WOS IDWOS:000259301000020
PublisherGEORG THIEME VERLAG KG
Citation statistics
Cited Times:66[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64194
Collection中国科学院化学研究所
Corresponding AuthorYe, Song
AffiliationChinese Acad Sci, Inst Chem, Biol Chem Lab, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
He, Lin,Zhang, Yan-Rong,Huang, Xue-Liang,et al. Chiral bifunctional N-heterocyclic carbenes: Synthesis and application in the aza-Morita-Baylis-Hillman reaction[J]. SYNTHESIS-STUTTGART,2008(17):2825-2829.
APA He, Lin,Zhang, Yan-Rong,Huang, Xue-Liang,&Ye, Song.(2008).Chiral bifunctional N-heterocyclic carbenes: Synthesis and application in the aza-Morita-Baylis-Hillman reaction.SYNTHESIS-STUTTGART(17),2825-2829.
MLA He, Lin,et al."Chiral bifunctional N-heterocyclic carbenes: Synthesis and application in the aza-Morita-Baylis-Hillman reaction".SYNTHESIS-STUTTGART .17(2008):2825-2829.
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