ICCAS OpenIR
Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation
Li, Weiwei1; Han, Yang1; Li, Binsong1; Liu, Caiming2; Bo, Zhishan1
2008-07-01
Source PublicationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN0887-624X
Volume46Issue:13Pages:4556-4563
AbstractZero-valent palladium complex, Pd(PTh3)(3), with three tri(2-thienyl)phosphine ligands was prepared and characterized. Pd(PTh3)(3) is superior to Pd(PPh3)(4) in catalyzing Suzuki-Miyaura coupling and polymerization of thiophene-based derivatives. The Suzuki polycondensation of 3-hexyl-5-iodothiophene-2-boronic pinacol ester with Pd(PTh3)(3) as the catalyst precursor afforded high-molecular-weight P3HT with high regularity and yield. (C) 2008 Wiley Periodicals, Inc.
KeywordConducting Polymers Conjugated Polymers Polycondensation
DOI10.1002/pola.22792
Indexed BySCI
Language英语
WOS IDWOS:000257153500027
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64156
Collection中国科学院化学研究所
Corresponding AuthorBo, Zhishan
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Li, Weiwei,Han, Yang,Li, Binsong,et al. Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2008,46(13):4556-4563.
APA Li, Weiwei,Han, Yang,Li, Binsong,Liu, Caiming,&Bo, Zhishan.(2008).Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,46(13),4556-4563.
MLA Li, Weiwei,et al."Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 46.13(2008):4556-4563.
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