ICCAS OpenIR
Weak epitaxy growth and phase behavior of planar phthalocyanines on p-sexiphenyl monolayer film
Wang, Tong; Yang, Junliang; Wang, Haibo; Zhu, Feng; Yan, Donghang
2008-06-05
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY B
ISSN1520-6106
Volume112Issue:22Pages:6786-6792
AbstractWe systematically investigated the weak epitaxy growth (WEG) behavior of a series of planar phthalocyanine compounds (MPc), i.e., metal-free phthalocyanine (H2PC), nickel phthalocyanine (NiPc), copper phthalocyanine (CuPc), zinc phthalocyanine (ZnPc), iron phthalocyanine (FePc); cobalt phthalocyanine (CoPc), grown on a p-sexiphenyl (p-6P) monolayer film by selected area electron diffraction (SAED) and atomic force microscopy (AFM). Two types of epitaxial relations, named as incommensurate epitaxy and commensurate epitaxy, were identified between phthalocyanine compounds and the substrate of the p-6P film. The tiny variation of the lattice constant of phthalocyanine compounds can result in different crystal orientations. The change rule of incommensurate and commensurate epitaxy was extracted. The tendency of commensurate epitaxy becomes weaker as the lattice constant b increases, while it gets stronger as the substrate temperature is elevated. Large size and continuous H2PC films can be obtained by controlling the growth conditions. The WEG method is generally applicable in the whole family of planar phthalocyanine compounds and may be used to fabricate other high-quality organic films.
DOI10.1021/jp7118795
Indexed BySCI
Language英语
WOS IDWOS:000256265000009
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64118
Collection中国科学院化学研究所
Corresponding AuthorYan, Donghang
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Wang, Tong,Yang, Junliang,Wang, Haibo,et al. Weak epitaxy growth and phase behavior of planar phthalocyanines on p-sexiphenyl monolayer film[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2008,112(22):6786-6792.
APA Wang, Tong,Yang, Junliang,Wang, Haibo,Zhu, Feng,&Yan, Donghang.(2008).Weak epitaxy growth and phase behavior of planar phthalocyanines on p-sexiphenyl monolayer film.JOURNAL OF PHYSICAL CHEMISTRY B,112(22),6786-6792.
MLA Wang, Tong,et al."Weak epitaxy growth and phase behavior of planar phthalocyanines on p-sexiphenyl monolayer film".JOURNAL OF PHYSICAL CHEMISTRY B 112.22(2008):6786-6792.
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