ICCAS OpenIR
Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3
Zhou Hui-Qiong1; Su Xu1; Chen Xing-Guo1; Inokuchi, Makoto2; Zhang De-Qing3; Qin Jin-Gui1
2008-08-10
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume24Issue:8Pages:1261-1264
AbstractThe synthesis and magnetism of an intercalation compound were studied based on 2-(4'-N-methylypridinium)-4,4,5,5-tetramethyl-imidazolinyl-1-oxyl-3-oxide (Methylpyridinium nitronyl nitroxide, MPYNN) radical into layered MnPS3. The lattice expansion of 0.56 nm suggests that the guest molecule plane of pyridine in MPYNN is arranged almost perpendicular to the host layer. Magnetic measurements by SQUID indicates that the intercalation compound of (MPYNN)(0.14)Mn0.93PS3 exhibits paramagnetism above 10 K, and then spontaneous magnetization occurs at 7 K.
KeywordIntercalation Nitrorryl Nitroxide Radical Layered Mnps3 Magnetic Property
Indexed BySCI
Language英语
WOS IDWOS:000258639900012
PublisherCHINESE CHEMICAL SOC
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64112
Collection中国科学院化学研究所
Corresponding AuthorChen Xing-Guo
Affiliation1.Wuhan Univ, Hubei Key Lab Organ & Polymer Optoelect Mat, Dept Chem, Wuhan 43007, Peoples R China
2.Tokyo Univ Sci, Dept Mat Sci & Environm Engn, Yamaguchi 7560884, Japan
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhou Hui-Qiong,Su Xu,Chen Xing-Guo,et al. Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2008,24(8):1261-1264.
APA Zhou Hui-Qiong,Su Xu,Chen Xing-Guo,Inokuchi, Makoto,Zhang De-Qing,&Qin Jin-Gui.(2008).Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3.CHINESE JOURNAL OF INORGANIC CHEMISTRY,24(8),1261-1264.
MLA Zhou Hui-Qiong,et al."Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3".CHINESE JOURNAL OF INORGANIC CHEMISTRY 24.8(2008):1261-1264.
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