ICCAS OpenIR
Effect of annealing on the deformation mechanism of a styrene/n-butyl acrylate copolymer latex film investigated by synchrotron small-angle X-ray scattering
Zhang, Jianqi1; Hu, Shanshan1; Rieger, Jens2; Roth, Stephan V.3; Gehrke, Rainer3; Men, Yongfeng1
2008-06-24
Source PublicationMACROMOLECULES
ISSN0024-9297
Volume41Issue:12Pages:4353-4357
AbstractThe deformation mechanism of a styrene/n-butyl acrylate copolymer latex film subjected to uniaxial tensile stress was studied by small-angle X-ray scattering. The influence of annealing at 23, 60, 80, and 100 degrees C for 4 h on microscopic deformation processes was elucidated. It was demonstrated that the microscopic deformation mechanism of the latex films transformed gradually from nonaffine deformation behavior to affine deformation behavior with increasing annealing temperature. This behavior was attributed to the interdiffusion of polymeric chains between adjacent latex particles in the film, the extent of which increases with annealing temperature. The polycrystalline structure of the latex films was preserved even after annealing for 4 h at temperatures 80 K above the glass transition temperature; i.e., the structure is not completely homogenized by interdiffusion.
DOI10.1021/ma800435f
Indexed BySCI
Language英语
WOS IDWOS:000256843100041
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64026
Collection中国科学院化学研究所
Corresponding AuthorMen, Yongfeng
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.BASF SE, D-67056 Ludwigshafen, Germany
3.DESY, HASYLAB, D-22607 Hamburg, Germany
Recommended Citation
GB/T 7714
Zhang, Jianqi,Hu, Shanshan,Rieger, Jens,et al. Effect of annealing on the deformation mechanism of a styrene/n-butyl acrylate copolymer latex film investigated by synchrotron small-angle X-ray scattering[J]. MACROMOLECULES,2008,41(12):4353-4357.
APA Zhang, Jianqi,Hu, Shanshan,Rieger, Jens,Roth, Stephan V.,Gehrke, Rainer,&Men, Yongfeng.(2008).Effect of annealing on the deformation mechanism of a styrene/n-butyl acrylate copolymer latex film investigated by synchrotron small-angle X-ray scattering.MACROMOLECULES,41(12),4353-4357.
MLA Zhang, Jianqi,et al."Effect of annealing on the deformation mechanism of a styrene/n-butyl acrylate copolymer latex film investigated by synchrotron small-angle X-ray scattering".MACROMOLECULES 41.12(2008):4353-4357.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Jianqi]'s Articles
[Hu, Shanshan]'s Articles
[Rieger, Jens]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Jianqi]'s Articles
[Hu, Shanshan]'s Articles
[Rieger, Jens]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Jianqi]'s Articles
[Hu, Shanshan]'s Articles
[Rieger, Jens]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.