ICCAS OpenIR
Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex
Liu, Zhiwei; Bian, Zuqiang; Bian, Jiang; Li, Zhendong; Nie, Daobo; Huang, Chunhui
2008-09-15
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume47Issue:18Pages:8025-8030
AbstractAn iridium complex Plr(qnx) (iridium(III) bis(2-phenylpyridinato-N C-2) (quinoxaline-2-carboxylate)) is reported for its unique and fast vapochromic and vapoluminescent behaviors. The emission of Plr(qnx) is governed by the whole crystal rather than the individual molecule. Plr(qnx) has been found to exist as both black and red forms in the solid state. The black form can be transformed into the red form upon its exposure to acetonitrile or propiononitrile vapor, whereas no response was observed when it was exposed to other volatile organic Compounds. To understand the vapochromic and vapoluminescent behaviors, we determined crystal structures of both forms by X-ray diffraction. In addition, we employed density functional theory in investigating weak intermolecular interactions, such as hydrogen bonding and pi-pi interactions in the two forms.
DOI10.1021/ic702141h
Indexed BySCI
Language英语
WOS IDWOS:000259093700018
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:50[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/64004
Collection中国科学院化学研究所
Corresponding AuthorBian, Zuqiang
AffiliationPeking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Liu, Zhiwei,Bian, Zuqiang,Bian, Jiang,et al. Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex[J]. INORGANIC CHEMISTRY,2008,47(18):8025-8030.
APA Liu, Zhiwei,Bian, Zuqiang,Bian, Jiang,Li, Zhendong,Nie, Daobo,&Huang, Chunhui.(2008).Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex.INORGANIC CHEMISTRY,47(18),8025-8030.
MLA Liu, Zhiwei,et al."Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex".INORGANIC CHEMISTRY 47.18(2008):8025-8030.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Zhiwei]'s Articles
[Bian, Zuqiang]'s Articles
[Bian, Jiang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Zhiwei]'s Articles
[Bian, Zuqiang]'s Articles
[Bian, Jiang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Zhiwei]'s Articles
[Bian, Zuqiang]'s Articles
[Bian, Jiang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.