ICCAS OpenIR
An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine
Asma, Maliha1,2,3; Adewuyi, Sheriff1,2; Kuang, Xiaofei1,2; Badshah, Amin3; Sun, Wen-Hua1,2
2008-06-01
Source PublicationLETTERS IN ORGANIC CHEMISTRY
ISSN1570-1786
Volume5Issue:4Pages:296-299
Abstract2-Carbethoxy-6-acetylpyridine and 2,6-diacetylpyridine were transformed in good yields from the reaction of 2,6-dicarbethoxypyridine and EtOAc in the presence of sodium along with/without an equivalent of ethanol to sodium in toluene. The beta-keto esters, the intermediates in the transformation of beta-keto carboxylate into acetyl group, were isolated for understanding the plausible mechanism.
Keyword2-carbethoxy-6-acetylpyridine Claisen Ester Condensation Anti-claisen Reaction 2 2 6-diacetylpyridine 6-dicarbethoxypyridine
Indexed BySCI
Language英语
WOS IDWOS:000256193400011
PublisherBENTHAM SCIENCE PUBL LTD
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63908
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
3.Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
Recommended Citation
GB/T 7714
Asma, Maliha,Adewuyi, Sheriff,Kuang, Xiaofei,et al. An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine[J]. LETTERS IN ORGANIC CHEMISTRY,2008,5(4):296-299.
APA Asma, Maliha,Adewuyi, Sheriff,Kuang, Xiaofei,Badshah, Amin,&Sun, Wen-Hua.(2008).An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine.LETTERS IN ORGANIC CHEMISTRY,5(4),296-299.
MLA Asma, Maliha,et al."An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine".LETTERS IN ORGANIC CHEMISTRY 5.4(2008):296-299.
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