ICCAS OpenIR
2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity
Chen, Yanjun1,2; Hao, Peng1; Zuo, Weiwei1; Gao, Kun1,2; Sun, Wen-Hua1,2
2008-05-01
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume693Issue:10Pages:1829-1840
AbstractA series of 2-(1-isopropyl-2- benzimidazolyl)-6-(1-aryliminoethyl) pyridyl metal complexes [iron (II) (1a-6a), cobalt (II) (1b-6b) and nickel (II) (1c-6c)] were synthesized and fully characterized by elemental and spectroscopic analyses. Single-crystal X-ray diffraction analyses of five coordinated complexes 5a, 3b, 5b, 1c and 2c reveal 5a and 5b as distorted trigonal-bipyramidal geometry, and 3b, 1c and 2c as distorted square pyramidal geometry. All complexes performed ethylene reactivity with the assistance of various organoaluminums. The iron complexes displayed good activities in the presence of MAO and MMAO. Upon activated by Et(2)AlCl, the cobalt analogues showed moderate ethylene reactivity, while the nickel analogues exhibited relatively higher activities. (C) 2008 Elsevier B.V. All rights reserved.
KeywordTransition Metal Complex Iron Cobalt Nickel 2-(Benzimidazolyl)-6-iminopyridine Ethylene Reactivity
DOI10.1016/j.jorganchem.2008.02.007
Indexed BySCI ; IC
Language英语
WOS IDWOS:000255891700013
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:95[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63850
Collection中国科学院化学研究所
Corresponding AuthorGao, Kun
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Chen, Yanjun,Hao, Peng,Zuo, Weiwei,et al. 2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(10):1829-1840.
APA Chen, Yanjun,Hao, Peng,Zuo, Weiwei,Gao, Kun,&Sun, Wen-Hua.(2008).2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(10),1829-1840.
MLA Chen, Yanjun,et al."2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.10(2008):1829-1840.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chen, Yanjun]'s Articles
[Hao, Peng]'s Articles
[Zuo, Weiwei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chen, Yanjun]'s Articles
[Hao, Peng]'s Articles
[Zuo, Weiwei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen, Yanjun]'s Articles
[Hao, Peng]'s Articles
[Zuo, Weiwei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.