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Syntheses, structures and properties of seven isomorphous 1D Ln(3+) complexes Ln(BTA)(HCOO)(H2O)(3) (H(2)BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln(3+) complexes Ln(HCOO)(3) (Ln = Pr, Nd)
Lin, Jiao-Min1; Guan, Yang-Fan1; Wang, Dong-Yao1; Dong, Wen1; Wang, Xiu-Teng2; Gao, Song2
2008
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Issue44Pages:6165-6169
AbstractSeven isomorphous 1D chain Ln(3+) complexes Ln(BTA)(HCOO)(H2O)(3) (Ln = Pr (1), Gd (2), Eu (3), Tb (4) Dy (5), Er (6) and Yb (7)), and two formate coordinating and bridging 3D Ln(3+) complexes Ln(HCOO)(3) (Ln = Pr (8) and Nd (9)) have been synthesized and characterized by single crystal X-ray diffraction analysis. Although the Ln(3+) ions in 1-7 have different radius, the trivalent lanthanide ions in 1-7 show the same coordinated environment. The well-defined single crystal structures of 8 and 9 are first samples for formate-bridged Ln(3+) metallic complexes. The luminescent properties of solid samples of 2-5 at room temperature and the magnetic property of 2 have been also reported and discussed in this paper.
DOI10.1039/b808394k
Indexed BySCI
Language英语
WOS IDWOS:000260644000014
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:51[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63682
Collection中国科学院化学研究所
Corresponding AuthorDong, Wen
Affiliation1.Guangzhou Univ, Dept Chem, Guangzhou 510006, Guangdong, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Lin, Jiao-Min,Guan, Yang-Fan,Wang, Dong-Yao,et al. Syntheses, structures and properties of seven isomorphous 1D Ln(3+) complexes Ln(BTA)(HCOO)(H2O)(3) (H(2)BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln(3+) complexes Ln(HCOO)(3) (Ln = Pr, Nd)[J]. DALTON TRANSACTIONS,2008(44):6165-6169.
APA Lin, Jiao-Min,Guan, Yang-Fan,Wang, Dong-Yao,Dong, Wen,Wang, Xiu-Teng,&Gao, Song.(2008).Syntheses, structures and properties of seven isomorphous 1D Ln(3+) complexes Ln(BTA)(HCOO)(H2O)(3) (H(2)BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln(3+) complexes Ln(HCOO)(3) (Ln = Pr, Nd).DALTON TRANSACTIONS(44),6165-6169.
MLA Lin, Jiao-Min,et al."Syntheses, structures and properties of seven isomorphous 1D Ln(3+) complexes Ln(BTA)(HCOO)(H2O)(3) (H(2)BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln(3+) complexes Ln(HCOO)(3) (Ln = Pr, Nd)".DALTON TRANSACTIONS .44(2008):6165-6169.
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