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Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane, ethylene, and acetylene
Dong, Feng1; Heinbuch, Scott1; Xie, Yan1; Rocca, Jorge J.1; Bernstein, Elliot R.1; Wang, Zhe-Chen2; Deng, Ke3; He, Sheng-Gui2
2008-02-13
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume130Issue:6Pages:1932-1943
AbstractReactions of neutral vanadium oxide clusters with small hydrocarbons, namely C2H6, C2H4, and C2H2, are investigated by experiment and density functional theory (DFT) calculations. Single photon ionization through extreme ultraviolet (EUV, 46.9 nm, 26.5 eV) and vacuum ultraviolet (VUV, 118 nm, 10.5 eV) lasers is used to detect neutral cluster distributions and reaction products. The most stable vanadium oxide clusters VO2, V2O5, V3O7, V4O10, etc. tend to associate with C2H4 generating products VmOnC2H4. Oxygen-rich clusters VO3(V2O5)(n=0,1,2 center dot center dot center dot,) (e.g., VO3, V3O8, and V5O13) react with C2H4 molecules to cause a cleavage of the C=C bond Of C2H4 to produce (V2O5)(n)VO2CH2 clusters. For the reactions of vanadium oxide clusters (VmOn) with C2H2 molecules, VmOnC2H2 are assigned as the major products of the association reactions. Additionally, a dehydration reaction for VO3 + C2H2 to produce VO2C2 is also identified. C2H6 molecules are quite stable toward reaction with neutral vanadium oxide clusters. Density functional theory calculations are employed to investigate association reactions for V2O5 + C2Hx. The observed relative reactivity of C-2 hydrocarbons toward neutral vanadium oxide clusters is well interpreted by using the DFT calculated binding energies. DFT calculations of the pathways for VO3+C2H4 and VO3+C2H2 reaction systems indicate that the reactions VO3+C2H4 -> VO2CH2 + H2CO and VO3+C2H2 -> VO2C2 + H2O are thermodynamically favorable and overall barrierless at room temperature, in good agreement with the experimental observations.
DOI10.1021/ja076007z
Indexed BySCI
Language英语
WOS IDWOS:000253100200031
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:122[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63540
Collection中国科学院化学研究所
Corresponding AuthorBernstein, Elliot R.
Affiliation1.Colorado State Univ, Dept Chem, Dept Elect & Comp Engn, NSF ERC Extreme Ultraviolet Sci & Technol, Ft Collins, CO 80523 USA
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
3.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Dong, Feng,Heinbuch, Scott,Xie, Yan,et al. Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane, ethylene, and acetylene[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(6):1932-1943.
APA Dong, Feng.,Heinbuch, Scott.,Xie, Yan.,Rocca, Jorge J..,Bernstein, Elliot R..,...&He, Sheng-Gui.(2008).Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane, ethylene, and acetylene.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(6),1932-1943.
MLA Dong, Feng,et al."Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane, ethylene, and acetylene".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.6(2008):1932-1943.
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