ICCAS OpenIR
Mesostructured spheres of organic/inorganic hybrid from gelable block copolymers and arched nano-objects thereof
Zhang, Ke; Yu, Xianglin; Gao, Lei; Chen, Yongming; Yang, Zhenzhong
2008-07-01
Source PublicationLANGMUIR
ISSN0743-7463
Volume24Issue:13Pages:6542-6548
AbstractMesostructured microspheres formed by aerosol-assisted self-assembly of a gelable block copolymer, poly(3(triethoxysilyl)propyl methaerylate)-block-polystyrene (PTEPM-b-PS), were studied by a combination of small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM). When the copolymer composition was changed, the spheres with different internal patterns, such as onion-like lamella and curved cylinder, were obtained. Through a self-gelation process of PTEPM domains, novel organic/inorganic hybrid spheres with an internal tunable patterned structure were prepared. Since only PTEMP domains were cross-linked, the hybrid spheres could be further disintegrated by dispersion in a good solvent of PS. As a result, novel organic/inorganic hybrid nano-objects such as arched plates and cylinders were prepared.
DOI10.1021/la800096w
Indexed BySCI
Language英语
WOS IDWOS:000257101100023
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63458
Collection中国科学院化学研究所
Corresponding AuthorChen, Yongming
AffiliationChinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Ke,Yu, Xianglin,Gao, Lei,et al. Mesostructured spheres of organic/inorganic hybrid from gelable block copolymers and arched nano-objects thereof[J]. LANGMUIR,2008,24(13):6542-6548.
APA Zhang, Ke,Yu, Xianglin,Gao, Lei,Chen, Yongming,&Yang, Zhenzhong.(2008).Mesostructured spheres of organic/inorganic hybrid from gelable block copolymers and arched nano-objects thereof.LANGMUIR,24(13),6542-6548.
MLA Zhang, Ke,et al."Mesostructured spheres of organic/inorganic hybrid from gelable block copolymers and arched nano-objects thereof".LANGMUIR 24.13(2008):6542-6548.
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