ICCAS OpenIR
Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst
Zhang, Shufeng2; Guo, Cunyue1; Qian, Qingh1; Yuan, Guoqing1
2008-03-20
Source PublicationCATALYSIS COMMUNICATIONS
ISSN1566-7367
Volume9Issue:5Pages:853-858
AbstractNovel porous spherules fabricated via crosslinking copolymerization of 2-vinyl pyridine and ethylene glycol diacrylate and the subsequent formation of chelate complex with [Rh(CO)(2)Cl(2)](-) were reported in this paper. The complex is well swelled in the reaction medium. Advantages of this catalyst lied in the fact that it could rapidly catalyze carbonylation of methanol to acetic acid with high selectivity and directly formed some acetic anhydride under mild conditions ( >= 140 degrees C). In addition, occurrence of water gas shift reaction during the process is hardly observable. (c) 2007 Elsevier B.V. All rights reserved.
KeywordMethanol Carbonylation Rhodium/polymer Catalyst Catalytic Activity
DOI10.1016/j.catcom.2007.09.010
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000253450900055
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63340
Collection中国科学院化学研究所
Corresponding AuthorYuan, Guoqing
Affiliation1.Chinese Acad Sci, Inst Chem, Lab New Mat, Beijing 100080, Peoples R China
2.Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shufeng,Guo, Cunyue,Qian, Qingh,et al. Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst[J]. CATALYSIS COMMUNICATIONS,2008,9(5):853-858.
APA Zhang, Shufeng,Guo, Cunyue,Qian, Qingh,&Yuan, Guoqing.(2008).Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst.CATALYSIS COMMUNICATIONS,9(5),853-858.
MLA Zhang, Shufeng,et al."Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst".CATALYSIS COMMUNICATIONS 9.5(2008):853-858.
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