ICCAS OpenIR
Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives
Li, Zhi-Wei1; Wang, Tian-Li1; He, Yan-Mei1; Wang, Zhi-Jian1; Fan, Qing-Hua1; Pan, Jie1; Xu, Li-Jun2
2008-11-20
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume10Issue:22Pages:5265-5268
AbstractEnantioselective hydrogenation of quinoline derivatives catalyzed by phosphine-free chiral cationic Cp*Ir(OTf)(CF(3)TsDPEN) complex (CF3TsDPEN = N-(p-trifluoromethylbenzenesulfonyl)-1,2-diphenylethylene-diamine) afforded the 1,2,3,4-tetrahydroquinoline derivatives in up to 99% ee. The reaction could be carried out with a substrate-to-catalyst molar ratio as high as 1000 in undegassed methanol and with no need for inert gas protection.
DOI10.1021/ol802016w
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000260922500043
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:109[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63256
Collection中国科学院化学研究所
Corresponding AuthorFan, Qing-Hua
Affiliation1.Chinese Acad Sci, Ctr Chem Biol, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Renmin Univ China, Dept Chem, Beijing 100972, Peoples R China
Recommended Citation
GB/T 7714
Li, Zhi-Wei,Wang, Tian-Li,He, Yan-Mei,et al. Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives[J]. ORGANIC LETTERS,2008,10(22):5265-5268.
APA Li, Zhi-Wei.,Wang, Tian-Li.,He, Yan-Mei.,Wang, Zhi-Jian.,Fan, Qing-Hua.,...&Xu, Li-Jun.(2008).Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives.ORGANIC LETTERS,10(22),5265-5268.
MLA Li, Zhi-Wei,et al."Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives".ORGANIC LETTERS 10.22(2008):5265-5268.
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