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A series of novel Ln-succinate-oxalate coordination polymers: synthesis, structure, thermal stability, and fluorescent properties
Zhang, Xing-Jing1,2; Xing, Yong-Heng1; Han, Jing1; Zeng, Xiao-Qing3; Ge, Mao-Fa3; Niu, Shu-Yun1
2008-10-01
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume8Issue:10Pages:3680-3688
AbstractA series of novel coordination polymers [Ln(suc)(ox)(0.5)(H2O)] (Ln = Sm (1) and Th (2)); [Pr(suc)(ox)(0.5)(H2O)(2)]center dot 2H(2)O (3); and [KLn(suc)(0.5)(ox)(1.5)(H2O)]center dot H2O (Ln = Nd (4), Eu (5), Tb (6) and Gd(7)) have been synthesized by the reaction of nitrate salts of Ln(III) with succinic acid and oxalic acid under hydrothermal conditions and were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Structural analyses reveal that all seven complexes have 3D net structures, and in these complexes, they were crystallized in trictinic space group P (1) over bar for complexes 1 and 2, orthorhombic space group Fddd for complex 3, and orthorhombic space group Pbam for complex 4-7, respectively. In particular, for 4-7, K ions were introduced into the structures of complexes and made the structures more novel and complicated. Thus the complexes have the same ligands but different structures. The results show that coordination modes of the linear succinic acid and oxalic acid ligands are versatile and can adopt different conformations according to different lanthanide ions. The thermogravimetric analysis of 1-7 and photoluminescent properties of 2, 5 and 6 are discussed in detail.
DOI10.1021/cg800294c
Indexed BySCI
Language英语
WOS IDWOS:000259672900037
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:47[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63164
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Jilin Normal Univ, Coll Chem, Siping 136000, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Xing-Jing,Xing, Yong-Heng,Han, Jing,et al. A series of novel Ln-succinate-oxalate coordination polymers: synthesis, structure, thermal stability, and fluorescent properties[J]. CRYSTAL GROWTH & DESIGN,2008,8(10):3680-3688.
APA Zhang, Xing-Jing,Xing, Yong-Heng,Han, Jing,Zeng, Xiao-Qing,Ge, Mao-Fa,&Niu, Shu-Yun.(2008).A series of novel Ln-succinate-oxalate coordination polymers: synthesis, structure, thermal stability, and fluorescent properties.CRYSTAL GROWTH & DESIGN,8(10),3680-3688.
MLA Zhang, Xing-Jing,et al."A series of novel Ln-succinate-oxalate coordination polymers: synthesis, structure, thermal stability, and fluorescent properties".CRYSTAL GROWTH & DESIGN 8.10(2008):3680-3688.
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