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An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)]
Yang, Sihai; Li, Guobao; Ju, Jing; Yang, Ziliang; Liao, Fuhui; Wang, Yingxia; Lin, Jianhua
2008-06-02
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume361Issue:8Pages:2413-2417
AbstractA new aluminoborate, [C(5)H(6)N][AlB(12)O(14)(OH)(12)], has been hydrothermally synthesized at 200 degrees C. The single-crystal diffraction study reveals that it crystallizes in space group C2/c. It consists of aluminoborate clusters [AlB(12)O(14)(OH)(12)](-) and counterions [C(5)H(6)N](+). The aluminoborate cluster contains an Al(OH)(6) octahedron as a core that is capped by two raft-like polyborate units [B(6)O(7)(OH)(6)]. These clusters are further interlinked by extensive hydrogen bonding to form a three-dimensional (3D) network, containing large channels along the b-axis, in which the [C(5)H(6)N](+) cations are located. (C) 2007 Elsevier B.V. All rights reserved.
KeywordPolyborate Aluminoborate Hydrothermal Reaction Cluster Supramolecular
DOI10.1016/j.ica.2007.12.025
Indexed BySCI
Language英语
WOS IDWOS:000256093600028
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/63088
Collection中国科学院化学研究所
Corresponding AuthorLi, Guobao
AffiliationPeking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Yang, Sihai,Li, Guobao,Ju, Jing,et al. An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)][J]. INORGANICA CHIMICA ACTA,2008,361(8):2413-2417.
APA Yang, Sihai.,Li, Guobao.,Ju, Jing.,Yang, Ziliang.,Liao, Fuhui.,...&Lin, Jianhua.(2008).An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)].INORGANICA CHIMICA ACTA,361(8),2413-2417.
MLA Yang, Sihai,et al."An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)]".INORGANICA CHIMICA ACTA 361.8(2008):2413-2417.
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