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Development of nanodomain and fractal morphologies in solvent annealed block copolymer thin films | |
Peng, Juan; Han, Yanchun; Knoll, Wolfgang; Kim, Dong Ha | |
2007-07-02 | |
Source Publication | MACROMOLECULAR RAPID COMMUNICATIONS
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ISSN | 1022-1336 |
Volume | 28Issue:13Pages:1422-1428 |
Abstract | We have systematically studied the thin film morphologies of asymmetric polystyrene-block-poly(ethylene oxide) (PS-b-PEO) diblock copolymer subjected to solvent vapors of varying selectivity for the constituent blocks. Upon a short treatment in neutral or PS-selective vapor, the film exhibited a highly ordered array of hexagonally packed, cylindrical microdomains. In the case of PEO selective vapor annealing, such ordered cylindrical microdomains were not obtained. instead, fractal patterns on the microscale were observed and their growth processes investigated. Furthermore, hierarchical structures could be obtained if the fractal pattern was exposed to neutral or PS selective vapor. |
Keyword | Atomic Force Microscopy Fractal Patterns Hierarchical Nanostructures Ps-b-peo Block Copolymers Solvent Annealing |
DOI | 10.1002/marc.200700206 |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000247979300007 |
Publisher | WILEY-V C H VERLAG GMBH |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.iccas.ac.cn/handle/121111/62968 |
Collection | 中国科学院化学研究所 |
Corresponding Author | Han, Yanchun |
Affiliation | 1.Max Planck Inst Polymer Res, D-55128 Mainz, Germany 2.Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Ewha Womans Univ, Div Nano Sci, Seoul 120750, South Korea 4.Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea |
Recommended Citation GB/T 7714 | Peng, Juan,Han, Yanchun,Knoll, Wolfgang,et al. Development of nanodomain and fractal morphologies in solvent annealed block copolymer thin films[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2007,28(13):1422-1428. |
APA | Peng, Juan,Han, Yanchun,Knoll, Wolfgang,&Kim, Dong Ha.(2007).Development of nanodomain and fractal morphologies in solvent annealed block copolymer thin films.MACROMOLECULAR RAPID COMMUNICATIONS,28(13),1422-1428. |
MLA | Peng, Juan,et al."Development of nanodomain and fractal morphologies in solvent annealed block copolymer thin films".MACROMOLECULAR RAPID COMMUNICATIONS 28.13(2007):1422-1428. |
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