ICCAS OpenIR
Synthesis and crystal structure of a novel a-zeolite-like copper complex: [Cu-12(SO4)(12)(3H(2)O)]center dot H2O
Zhang, Xing-Jing; Xing, Yong-Heng; Han, Jing; Ge, Mao-Fa; Niu, Shu-Yun
2007
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Volume633Issue:15Pages:2692-2694
AbstractThe reaction of CuBr2, N(CH2CH2COOH)(3), and Nd(NO3)(3)-6H(2)O in water adjusted pH = 5-6 with H2SO4 at constant 55 C afforded a novel three-dimensional coordination complex [Cu-12(SO4)(12)(3H(2)O)]center dot H2O, (1), which was characterized by IR, elemental analysis, and X-ray diffraction. The crystal structure data of 1 as follows: Cubic, Fm3c, a = b = c = 24.018(2) angstrom, V = 13855 (3) angstrom(3), Z = 968, D, = 1.905 g/cm(3), F(000) = 7712, R-1 = 0.0352, wR(2) = 0.0866 (I > 2 sigma(I)), R-1 = 0.0449, wR(2) = 0.0927 (for all data) and S = 1.075. The analysis of crystal structure indicates that the structure of 1 is similar to that of silicate zeolite (Na-12[Al12Si12O48]center dot 27H(2)O).
KeywordCopper Crystal Structure Zeolite-like Framework
DOI10.1002/zaac.200700168
Indexed BySCI
Language英语
WOS IDWOS:000250808900029
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/62910
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Jilin Normal Univ, Coll Chem, Siping, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Xing-Jing,Xing, Yong-Heng,Han, Jing,et al. Synthesis and crystal structure of a novel a-zeolite-like copper complex: [Cu-12(SO4)(12)(3H(2)O)]center dot H2O[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2007,633(15):2692-2694.
APA Zhang, Xing-Jing,Xing, Yong-Heng,Han, Jing,Ge, Mao-Fa,&Niu, Shu-Yun.(2007).Synthesis and crystal structure of a novel a-zeolite-like copper complex: [Cu-12(SO4)(12)(3H(2)O)]center dot H2O.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,633(15),2692-2694.
MLA Zhang, Xing-Jing,et al."Synthesis and crystal structure of a novel a-zeolite-like copper complex: [Cu-12(SO4)(12)(3H(2)O)]center dot H2O".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 633.15(2007):2692-2694.
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