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Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes
Zhang, Lin; Chen, Ning; Fan, Louzhen; Wang, Chunru; Yang, Shihe
2007-09-15
Source PublicationJOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN1572-6657
Volume608Issue:1Pages:15-21
AbstractElectrochemical behavior Of Sc3N@C-78 Solution was investigated for the first time by cyclic voltammetry (CV) as well as differential pulse voltammetry (DPV). Reversible redox features Of Sc3N@C-78 were obtained in contrast to that of Dy3N@C-78, for which the corresponding redox waves were very recently found to be irreversible. Toluene/MeCN and four other solvents have been identified, wherewith reversible redox waves can also be observed for Sc3N@C-80 (I-n) at a normal potential scan rate, whereas o-dichlorobenzene (o-DCB) was found to give only irreversible redox behavior as concluded by other researchers. The redox properties Of Sc3N@C78 and Sc3N@C-80 (I-n) are comparatively discussed on the basis of their different electronic structures and interactions with the solvent molecules. Additionally, electrochemical energy gaps of both Sc3N@C78 and Sc3N@C-80 (I-n) were obtained. (c) 2007 Elsevier B.V. All rights reserved.
KeywordTrimetal Nitride Endohedral Fullerenes Electrochemistry Reversibility Sc3n@c-78 Sc3n@c-80
DOI10.1016/j.jelechem.2007.04.015
Indexed BySCI
Language英语
WOS IDWOS:000250241200003
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/62850
Collection中国科学院化学研究所
Corresponding AuthorYang, Shihe
Affiliation1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
2.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Lin,Chen, Ning,Fan, Louzhen,et al. Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2007,608(1):15-21.
APA Zhang, Lin,Chen, Ning,Fan, Louzhen,Wang, Chunru,&Yang, Shihe.(2007).Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,608(1),15-21.
MLA Zhang, Lin,et al."Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 608.1(2007):15-21.
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