ICCAS OpenIR
A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt
Wang, Si-Qian; Wang, Zi-Wei; Yang, Lin-Chun; Dong, Jin-Long; Chi, Cai-Qin; Sui, Dan-Ni; Wang, Yong-Zhao; Ren, Jian-Guo; Hung, Mei-Yu; Jiang, Ying-Yan
2007-03-01
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume264Issue:1-2Pages:60-65
AbstractA new bio-polymer heterobimetallic complex wool-Pd-Co is found to be a novel efficient catalyst for asymmetric hydration of unsaturated carboxylic acids with high enantioselectivity by simple and clean process under mild conditions. Chemical and optical yields are affected by some parameters, such as the (Pd + Co) content in wool-Pd-Co, the Co/Pd molar ratio, reaction time, reaction temperature and amount of water. After five-time use of the complex, the chemical and optical yields of the products show no significant changes. Obviously, the methods provide an alternative way to produce chiral beta-hydroxycarboxylic acids. (c) 2006 Elsevier B.V. All rights reserved.
KeywordChiral Beta-hydroxycarboxylic Acid Asymmetric Hydration Unsaturated Carboxylic Acids Heterobimetallic Complex Wool-palladium-cobalt
DOI10.1016/j.molcata.2006.08.073
Indexed BySCI
Language英语
WOS IDWOS:000244838200011
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/62830
Collection中国科学院化学研究所
Corresponding AuthorRen, Jian-Guo
Affiliation1.ShanXi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wang, Si-Qian,Wang, Zi-Wei,Yang, Lin-Chun,et al. A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2007,264(1-2):60-65.
APA Wang, Si-Qian.,Wang, Zi-Wei.,Yang, Lin-Chun.,Dong, Jin-Long.,Chi, Cai-Qin.,...&Jiang, Ying-Yan.(2007).A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,264(1-2),60-65.
MLA Wang, Si-Qian,et al."A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 264.1-2(2007):60-65.
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