ICCAS OpenIR
Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Wang, Xiao; Du, Juanjuan; Liu, Han; Du, Da-Ming; Xu, Jiaxi
2007
Source PublicationHETEROATOM CHEMISTRY
ISSN1042-7163
Volume18Issue:7Pages:740-746
AbstractThe effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane as catalysts. The results indicate that the enantioselective order of different borane sources is borane-dimethyl sulfide < borane-N,N-diethylaniline < borane-THF for the asymmetric reduction of a ketone under the same conditions. (c) 2007 Wiley Periodicals, Inc.
DOI10.1002/hc.20370
Indexed BySCI
Language英语
WOS IDWOS:000251367100005
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/62316
Collection中国科学院化学研究所
Corresponding AuthorXu, Jiaxi
AffiliationPeking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Wang, Xiao,Du, Juanjuan,Liu, Han,et al. Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones[J]. HETEROATOM CHEMISTRY,2007,18(7):740-746.
APA Wang, Xiao,Du, Juanjuan,Liu, Han,Du, Da-Ming,&Xu, Jiaxi.(2007).Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones.HETEROATOM CHEMISTRY,18(7),740-746.
MLA Wang, Xiao,et al."Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones".HETEROATOM CHEMISTRY 18.7(2007):740-746.
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