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Combination of Orthogonal ABB and ABC Multicomponent Reactions toward Efficient Divergent Synthesis of Dendrimers with Structural Diversity
Deng, Xin-Xing; Du, Fu-Sheng; Li, Zi-Chen
2014-07-01
Source PublicationACS MACRO LETTERS
ISSN2161-1653
Volume3Issue:7Pages:667-670
AbstractSynthesis of dendrimers has been directed toward process efficiency and structural diversity. We report a divergent approach to the preparation of dendrimers with both ABC and ABB branching structures from nonbranching monomers by combination of efficient orthogonal ABC Passerini multicomponent reaction (MCR) and ABB thiol-yne MCR. Two kinds of dendrimers were synthesized efficiently: (1) dendrimers with two generations in three steps and (2) dendrimers with two generations containing one kind of internal functional group and two kinds of surface functional groups in five steps. This new synthetic method offers an efficient access to dendrimers with structural diversity.
DOI10.1021/mz500207z
Indexed BySCI
Language英语
WOS IDWOS:000339226200016
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/53234
Collection中国科学院化学研究所
Corresponding AuthorLi, Zi-Chen
AffiliationPeking Univ, Beijing Natl Lab Mol Sci BNLMS, Key Lab Polymer Chem & Phys,Minist Educ, Dept Polymer Sci & Engn,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Deng, Xin-Xing,Du, Fu-Sheng,Li, Zi-Chen. Combination of Orthogonal ABB and ABC Multicomponent Reactions toward Efficient Divergent Synthesis of Dendrimers with Structural Diversity[J]. ACS MACRO LETTERS,2014,3(7):667-670.
APA Deng, Xin-Xing,Du, Fu-Sheng,&Li, Zi-Chen.(2014).Combination of Orthogonal ABB and ABC Multicomponent Reactions toward Efficient Divergent Synthesis of Dendrimers with Structural Diversity.ACS MACRO LETTERS,3(7),667-670.
MLA Deng, Xin-Xing,et al."Combination of Orthogonal ABB and ABC Multicomponent Reactions toward Efficient Divergent Synthesis of Dendrimers with Structural Diversity".ACS MACRO LETTERS 3.7(2014):667-670.
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