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Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers
Yuan, Kuo1,2; Song, Tianqun1,2; Wang, Dawei3; Zhang, Xiaotao1,2; Gao, Xiong1,2; Zou, Ye4; Dong, Huanli4; Tang, Zhiyong3; Hu, Wenping1,2,4
2018-05-14
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume57Issue:20Pages:5708-5713
AbstractMetal-organic frameworks (MOFs) as selectivity regulators for catalytic reactions have attracted much attention, especially MOFs and metal nanoparticle (NP) shelled structures, e.g., MOFs@NPs@MOFs. Nevertheless, making hydrophilic MOF shells for gathering hydrophobic reactants is challenging. Described here is a new and viable approach employing conjugated micro- and mesoporous polymers with iron(III) porphyrin (FeP-CMPs) as a new shell to fabricate MIL-101@Pt@FeP-CMP. It is not only hydrophobic and porous for enriching reactants, but also possesses iron sites to activate C=O bonds, thereby regulating the selectivity for cinnamyl alcohol in the hydrogenation of cinnamaldehyde. Interestingly, MIL-101@Pt@FeP-CMPsponge can achieve a high turnover frequency (1516.1 h(-1)), with 97.3% selectivity for cinnamyl alcohol at 97.6% conversion.
KeywordHydrogenation Hydrophobicity Metal-organic Frameworks Nanoparticles Polymers
DOI10.1002/anie.201801289
Indexed BySCI
Language英语
WOS IDWOS:000431488200021
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/43116
Collection中国科学院化学研究所
Corresponding AuthorZhang, Xiaotao; Tang, Zhiyong; Hu, Wenping
Affiliation1.Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, Dept Chem, Sch Sci, Tianjin 300072, Peoples R China
2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
3.Chinese Acad Sci, Key Lab Nanosyst & Hierarchy Fabricat, CAS Ctr Excellence Nanosci, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Natl Lab Mol Sci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yuan, Kuo,Song, Tianqun,Wang, Dawei,et al. Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(20):5708-5713.
APA Yuan, Kuo.,Song, Tianqun.,Wang, Dawei.,Zhang, Xiaotao.,Gao, Xiong.,...&Hu, Wenping.(2018).Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(20),5708-5713.
MLA Yuan, Kuo,et al."Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.20(2018):5708-5713.
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