ICCAS OpenIR
Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles
Wang, Xiao-Dong1,2; Wu, Jin-Jin1,2; Sun, Xue1,2; Yang, Wen-Chao1,2; Zhu, Jie1,2; Wu, Lei1,2,3,4
2018-09-17
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume360Issue:18Pages:3518-3525
AbstractA direct coupling of allenylphosphine oxides and alkynes is disclosed here mediated by MOF encapsulated palladium nanocatalysts. The methodology using alpha-allenyl ethers as starting materials provides a heterogeneous approach to generate tri-conjugated enynes with medium to excellent yields. The reaction tolerates a variety of functional groups to afford a range of structurally diverse substituted conjugated enynes. MOF served as support plays a significant role in dispersing and stabilizing the Pd nanoparticles. When compared with the homogeneous system, the advantage is also witnessed exhibiting a steady and high TOF value as well as the efficient reusability. A remarkable pore-control effect of the MOF catalysts was also revealed, depending on the dimension of MOF, molecular size of allenylphosphine oxides, alkynes and enynes respectively. Benefitting from the heterogeneous manner, successful recycling of the MOF catalyst was further achieved with high reaction efficiency maintained.
KeywordConjugated Enynes Phosphinyl Allenes Mof Palladium Nanoparticles
DOI10.1002/adsc.201800486
Indexed BySCI
Language英语
WOS IDWOS:000444672200012
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/43002
Collection中国科学院化学研究所
Corresponding AuthorZhu, Jie; Wu, Lei
Affiliation1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China
2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China
3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Xiao-Dong,Wu, Jin-Jin,Sun, Xue,et al. Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles[J]. ADVANCED SYNTHESIS & CATALYSIS,2018,360(18):3518-3525.
APA Wang, Xiao-Dong,Wu, Jin-Jin,Sun, Xue,Yang, Wen-Chao,Zhu, Jie,&Wu, Lei.(2018).Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles.ADVANCED SYNTHESIS & CATALYSIS,360(18),3518-3525.
MLA Wang, Xiao-Dong,et al."Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles".ADVANCED SYNTHESIS & CATALYSIS 360.18(2018):3518-3525.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Xiao-Dong]'s Articles
[Wu, Jin-Jin]'s Articles
[Sun, Xue]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Xiao-Dong]'s Articles
[Wu, Jin-Jin]'s Articles
[Sun, Xue]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Xiao-Dong]'s Articles
[Wu, Jin-Jin]'s Articles
[Sun, Xue]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.