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Polymer precursor-derived HfC-SiC ultrahigh-temperature ceramic nanocomposites
Cai, Tao1,2; Liu, Dan1; Qiu, WenFeng2; Han, WeiJian2; Zhao, Tong2
AbstractDue to poor mechanical properties and antioxidation properties, etc of single phase ultrahigh-temperature ceramics (UHTCs), the second phase such as SiC was usually introduced for improving those properties. Herein, a novel stratagem for synthesis of binary HfC-SiC ceramics has been presented. A Hf-O-Hf polymer as a HfO2 precursor has been synthesized for preparing soluble HfC-SiC precursors with high solid content and low viscosity solutions without additional organic solvents. The structure of PHO was characterized by FTIR and H-1-NMR, the crystalline behavior and morphologies of polymer-derived ceramics were identified by XRD, SEM-EDS, and TEM. It was shown that PHO firstly transformed into HfO2, and then reacted with in situ carbon derived from DVB and PCS thus producing cubic HfC through carbothermal reduction. In addition, the obtained HfC-SiC nanopowders exhibited spherical morphology with a diameter less than 100 nm, while the Hf, Si, and C are homogeneously distributed.
KeywordCarbothermal Reduction Microstructure Polymer Precursor Phase Transformation Ultrahigh-temperature Ceramics
Indexed BySCI
Document Type期刊论文
Affiliation1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo, Zhejiang, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Adv Polymer Mat, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Cai, Tao,Liu, Dan,Qiu, WenFeng,et al. Polymer precursor-derived HfC-SiC ultrahigh-temperature ceramic nanocomposites[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2018,101(1):20-24.
APA Cai, Tao,Liu, Dan,Qiu, WenFeng,Han, WeiJian,&Zhao, Tong.(2018).Polymer precursor-derived HfC-SiC ultrahigh-temperature ceramic nanocomposites.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,101(1),20-24.
MLA Cai, Tao,et al."Polymer precursor-derived HfC-SiC ultrahigh-temperature ceramic nanocomposites".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 101.1(2018):20-24.
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