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Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3- under High-Temperature Conditions
Li, Hai-Fang; Jiang, Li-Xue; Zhao, Yan-Xia; Liu, Qing-Yu; Zhang, Ting; He, Sheng-Gui
MAR 1 2018
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume57Issue:10Pages:2662-2666
AbstractThe underlying mechanism for non-oxidative methane aromatization remains controversial owing to the lack of experimental evidence for the formation of the first C-C bond. For the first time, the elementary reaction of methane with atomic clusters (FeC3-) under high-temperature conditions to produce C-C coupling products has been characterized by mass spectrometry. With the elevation of temperature from 300K to 610K, the production of acetylene, the important intermediate proposed in a monofunctional mechanism of methane aromatization, was significantly enhanced, which can be well-rationalized by quantum chemistry calculations. This study narrows the gap between gas-phase and condensed-phase studies on methane conversion and suggests that the monofunctional mechanism probably operates in non-oxidative methane aromatization.
WOS IDWOS:000426252400024
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Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/38740
Collection其它
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GB/T 7714
Li, Hai-Fang,Jiang, Li-Xue,Zhao, Yan-Xia,et al. Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3- under High-Temperature Conditions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,MAR ,57(10):2662-2666.
APA Li, Hai-Fang,Jiang, Li-Xue,Zhao, Yan-Xia,Liu, Qing-Yu,Zhang, Ting,&He, Sheng-Gui.(MAR ).Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3- under High-Temperature Conditions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(10),2662-2666.
MLA Li, Hai-Fang,et al."Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3- under High-Temperature Conditions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.10(MAR ):2662-2666.
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