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题名: Two-Dimensional Alignment of Self-Assembled Organic Nanotubes through Langmuir-Blodgett Technique
作者: Zhou, Xiaoqin1, 2; Cao, Hai1; Yang, Dong1; Zhang, Li1; Jiang, Long1; Liu, Minghua1, 2, 3
刊名: LANGMUIR
发表日期: 2016-12-13
卷: 32, 期:49, 页:13065-13072
收录类别: SCI
英文摘要: A C-3-symmetric molecule was found to form organic nanotubes through supramolecular gel formation in organic solvents. These nanotubes can be dispersed in toluene without destroying the tubular nanostructures. Using the dispersions of these organic nanotubes as "spreading solutions", Langmuir-spreading films of these nanotubes were formed. Through repeated compression and expansion cycles, the nanotubes can be aligned to a certain extent. The formed Langmuir films could be subsequently transferred to a solid substrate, and the well-aligned nanotube films were constructed by Langmuir-Blodgett film deposition technique. Interestingly, many guests including polymers, water-soluble or oil-soluble organic molecules can be encapsulated into the nanotubes and further spread on a water subphase. Through elaborate control, large-scale parallel alignment of self-assembled organic nanotubes encapsulated by guests was also realized. This study implies that 2D hierarchical alignment of one-dimensional organic nanostructures can be realized using a simple method.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/36519
Appears in Collections:胶体、界面与化学热力学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Chem Thermodynam, Inst Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
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