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ICCAS OpenIR  > 分子纳米结构与纳米技术实验室  > 期刊论文
题名: Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols
作者: Sun, Yongbin1; Cao, Changyan1; Wei, Fang1; Huang, Peipei1; Yang, Shuliang1; Song, Weiguo1
关键词: Fullerene ; Hollow sphere ; TEMPO ; Heterogeneous catalyst ; Oxidation of alcohols
刊名: SCIENCE BULLETIN
发表日期: 2016-05-01
卷: 61, 期:10, 页:772-777
收录类别: SCI
英文摘要: Polymerized fullerene hollow spheres bonded with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) have been successfully synthesized via amination of C-60 with 4-amino-TEMPO in the presence of H2O2, and then cross-linked by 1,6-hexanediamine. The hollow spheres were analyzed by fourier transform infrared spectrometer, electron spin resonance and X-ray photoelectron spectroscopy analysis, which indicated the presence of N-O free radicals in the products. When used as a typical heterogeneous catalyst for selective oxidation of alcohols to the corresponding aldehydes or ketones, it exhibited excellent activities, selectivity and recyclability. This synthesis route is convenient and effective, and may provide a new approach to developing immobilized fullerene based heterogeneous catalysts with high activity and recyclability.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/36136
Appears in Collections:分子纳米结构与纳米技术实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
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