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题名: Plasma synthesis of Pd/PdO supported on porous graphene as electrocatalyst for methanol oxidation
作者: Yang, Fan1; Wang, Chunxia2; Dong, Sen1; Chi, Cheng1; Jia, Xilai1; Zhang, Liqiang1; Li, Yongfeng1
关键词: Carbon materials ; Nanoparticles ; Electrical properties
刊名: MATERIALS LETTERS
发表日期: 2016-07-01
卷: 174, 页:192-196
收录类别: SCI
英文摘要: Pd/PdO nanoparticles supported on porous graphene (PG) are synthesized by a gas-liquid interfacial plasma method using Pd(NO3)(2) center dot 2H(2)O as precursor. The Pd/PdO ratios can be controlled by changing the amount of Pd(NO3)(2) center dot 2H(2)O. The synthesized Pd/PdO electrocatalysts exhibit a high electrocatalytic activity for methanol oxidation. The Pd/PdO nanoparticles attached on PG support shows better activity than that on oxidation carbon nanotubes support for methanol oxidation. In addition, our findings show that the PdO present in the Pd nanoparticles can enhance the electrocatalytic activity. It is worth to mention that the Pd/PdO nanoparticles supported on porous graphene catalysts show better electrochemical stability than that of commercial Pd/C catalyst. (C) 2016 Elsevier B.V. All rights reserved.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/36093
Appears in Collections:其它_期刊论文

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作者单位: 1.China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
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