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题名: Reactivity of Heteronuclear Oxide Clusters with Small Molecules
作者: Zhao Yanxia1; He Shenggui1
关键词: atomic clusters ; heteronuclear oxides ; reactive oxygen species ; noble metals ; reaction mechanisms
刊名: PROGRESS IN CHEMISTRY
发表日期: 2016-04-01
卷: 28, 期:4, 页:401-414
收录类别: SCI
英文摘要: Gas phase study of the chemical reactions between heteronuclear oxide clusters and small molecules permits to address the behavior of oxides composed of multiple components in catalytic reactions at a strictly molecular level. In this review, we summarize the recent progress in activation and transformation of small molecules by heteronuclear oxide clusters. The local charge, local spin, and structural effects on the reactivity of important reactive oxygen species are discussed. The novel reaction pathways and reaction mechanisms appearing after doping with noble metals are also presented.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/36086
Appears in Collections:分子动态与稳态结构实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
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