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题名: Asymmetric Retro-Claisen Reaction by Chiral Primary Amine Catalysis
作者: Zhu, Yunbo1, 2; Zhang, Long1, 2; Luo, Sanzhong1, 2
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
发表日期: 2016-03-30
卷: 138, 期:12, 页:3978-3981
收录类别: SCI
英文摘要: The communication describes an enamine-based asymmetric retro-Claisen reaction of beta-diketones by primary amine catalysis. The reaction proceeds via a sequence of stereoselective C-C formation, C-C cleavage, and a highly stereospecific enamine protonation to afford chiral alpha-alkylated ketones or macrolides with high yields and enantioselectivities. A detailed mechanism was explored on the basis of experimental evidence and computational studies to account for the observed stereo control.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35995
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, BNLMS, Beijing 100190, Peoples R China
2.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
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