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题名: Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization
作者: Xu, Xing-Dong1; Yao, Chang-Jiang2; Chen, Li-Jun1; Yin, Guang-Qiang1; Zhong, Yu-Wu2; Yang, Hai-Bo1
关键词: electropolymerization ; metallacycles ; molecular sieving ; porous materials ; supramolecular chemistry
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2016-04-04
卷: 22, 期:15, 页:5211-5218
收录类别: SCI
英文摘要: The construction of well-controlled porous materials is very challenging. Herein, we report the successful preparation of structurally defined porous membranes based on hexakistriphenylamine metallacycles through electropolymerization. The newly designed porous materials were characterized by the typical cyclic voltammograms, XPS, SEM, and TEM investigations. Further investigations revealed that the metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35974
Appears in Collections:光化学实验室_期刊论文

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作者单位: 1.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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